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Tafel plot for an anodic process . The Tafel equation is an equation in electrochemical kinetics relating the rate of an electrochemical reaction to the overpotential. [1] The Tafel equation was first deduced experimentally and was later shown to have a theoretical justification. The equation is named after Swiss chemist Julius Tafel.
The upper graph shows the current density as function of the overpotential η . The anodic and cathodic current densities are shown as j a and j c, respectively for α=α a =α c =0.5 and j 0 =1mAcm −2 (close to values for platinum and palladium).
the slope field is an array of slope marks in the phase space (in any number of dimensions depending on the number of relevant variables; for example, two in the case of a first-order linear ODE, as seen to the right). Each slope mark is centered at a point (,,, …,) and is parallel to the vector
In enzyme kinetics, a secondary plot uses the intercept or slope from several Lineweaver–Burk plots to find additional kinetic constants. [1] [2]For example, when a set of v by [S] curves from an enzyme with a ping–pong mechanism (varying substrate A, fixed substrate B) are plotted in a Lineweaver–Burk plot, a set of parallel lines will be produced.
The plot is occasionally attributed to Augustinsson [5] and referred to the Woolf–Augustinsson–Hofstee plot [6] [7] [8] or simply the Augustinsson plot. [9] However, although Haldane, Woolf or Eadie were not explicitly cited when Augustinsson introduced the versus / equation, both the work of Haldane [10] and of Eadie [3] are cited at other places of his work and are listed in his ...
An example of MUSCL type state parabolic-reconstruction. It is possible to extend the idea of linear-extrapolation to higher order reconstruction, and an example is shown in the diagram opposite. However, for this case the left and right states are estimated by interpolation of a second-order, upwind biased, difference equation.
The software developed by Deb can be downloaded, [7] which implements the NSGA-II procedure with GAs, or the program posted on Internet, [8] which implements the NSGA-II procedure with ES. Just a general form of the equation, a plot of the objective function, boundaries of the object variables and the coordinates of global minima are given herein.
It has also been called Sen's slope estimator, [1] [2] slope selection, [3] [4] the single median method, [5] the Kendall robust line-fit method, [6] and the Kendall–Theil robust line. [7] It is named after Henri Theil and Pranab K. Sen , who published papers on this method in 1950 and 1968 respectively, [ 8 ] and after Maurice Kendall ...