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HSAB is an acronym for "hard and soft (Lewis) acids and bases".HSAB is widely used in chemistry for explaining the stability of compounds, reaction mechanisms and pathways. It assigns the terms 'hard' or 'soft', and 'acid' or 'base' to chemical species.
Lewis structure of a water molecule. Lewis structures – also called Lewis dot formulas, Lewis dot structures, electron dot structures, or Lewis electron dot structures (LEDs) – are diagrams that show the bonding between atoms of a molecule, as well as the lone pairs of electrons that may exist in the molecule.
Some sources indicate the Lewis base with a pair of dots (the explicit electrons being donated), which allows consistent representation of the transition from the base itself to the complex with the acid: Me 3 B + :NH 3 → Me 3 B:NH 3. A center dot may also be used to represent a Lewis adduct, such as Me 3 B·NH 3.
The above three-dimensional LDQ structures are useful for visualising the molecular structures, but they can be laborious to construct. Hence, Linnett introduced two-dimensional structures, analogous to Lewis structures, that used dots and crosses to represent the relative spin states of electrons.
It is classified as a hard Lewis acid and its acceptor properties are discussed in the ECW model yielding E A = 2.07 and C A = 1.06. TFE can be used in biochemical experiments to stabilize alpha helix. [7] [8] There are also stable beta sheets in TFE, suggesting that TFE stabilizes the secondary structure the sequence has a preference for. [8]
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Lone pairs (shown as pairs of dots) in the Lewis structure of hydroxide. In science, a lone pair refers to a pair of valence electrons that are not shared with another atom in a covalent bond [1] and is sometimes called an unshared pair or non-bonding pair. Lone pairs are found in the outermost electron shell of atoms.
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