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In physics and chemistry, an equation of state is a thermodynamic equation relating state variables, which describe the state of matter under a given set of physical conditions, such as pressure, volume, temperature, or internal energy. [1] [2] Most modern equations of state are formulated in the Helmholtz free energy.
In physics, the thermal equation of state is a mathematical expression of pressure P, temperature T, and, volume V.The thermal equation of state for ideal gases is the ideal gas law, expressed as PV=nRT (where R is the gas constant and n the amount of substance), while the thermal equation of state for solids is expressed as:
One way to write the van der Waals equation is: [8] [9] [10] = where is pressure, is temperature, and = / is molar volume. In addition is the Avogadro constant, is the volume, and is the number of molecules (the ratio / is a physical quantity with base unit mole (symbol mol) in the SI).
However, this equation of state continues to be widely used in models of solid explosives. Of more elaborate equations of state, the most used in earth physics is the Birch–Murnaghan equation of state. In shock physics of metals and alloys, another widely used equation of state is the Mie–Gruneisen equation of state.
Quantity (common name/s) (Common) symbol/s Defining equation SI unit Dimension Temperature gradient: No standard symbol K⋅m −1: ΘL −1: Thermal conduction rate, thermal current, thermal/heat flux, thermal power transfer
The equations relating the current state of a system to its most recent input and past states are called the state equations, and the equations expressing the values of the output variables in terms of the state variables and inputs are called the output equations. As shown below, the state equations and output equations for a linear time ...
In physics, the Saha ionization equation is an expression that relates the ionization state of a gas in thermal equilibrium to the temperature and pressure. [ 1 ] [ 2 ] The equation is a result of combining ideas of quantum mechanics and statistical mechanics and is used to explain the spectral classification of stars.
A temperature-corrected version that is used in computational mechanics has the form [6] [7]: 61 = [] +;:= where is the bulk speed of sound, is the initial density, is the current density, is Grüneisen's gamma at the reference state, = / is a linear Hugoniot slope coefficient, is the shock wave velocity, is the particle velocity, and is the internal energy per unit reference volume.