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Optical rotation, also known as polarization rotation or circular birefringence, is the rotation of the orientation of the plane of polarization about the optical axis of linearly polarized light as it travels through certain materials. Circular birefringence and circular dichroism are the manifestations of optical activity.
Definition. The CRC Handbook of Chemistry and Physics defines specific rotation as: For an optically active substance, defined by [α] θλ = α/γl, where α is the angle through which plane polarized light is rotated by a solution of mass concentration γ and path length l. Here θ is the Celsius temperature and λ the wavelength of the light ...
Rotational diffusion. A molecule with a red cross on its front undergoing 3 dimensional rotational diffusion. The red cross moves erratically as the sphere is made to randomly rotate by collisions with surrounding molecules. Rotational diffusion is the rotational movement which acts upon any object such as particles, molecules, atoms when ...
Right: The reduction in flux passing through a surface can be visualized by reduction in F or dS equivalently (resolved into components, θ is angle to normal n). F•dS is the component of flux passing through the surface, multiplied by the area of the surface (see dot product). For this reason flux represents physically a flow per unit area.
Three scenarios were suggested by Newton to answer the question of whether the absolute rotation of a local frame can be detected; that is, if an observer can decide whether an observed object is rotating or if the observer is rotating. [29] [30] The shape of the surface of water rotating in a bucket. The shape of the surface becomes concave to ...
If there are -many optically active different chemicals ('chemical species') in a solution and the molar concentration (the number of moles of each chemical per liter of liquid solution) of each chemical in the solution is known and written as (where is a number used to identify the chemical species); and if each species has a specific rotation ...
Calculations. The stiffness, of a body is a measure of the resistance offered by an elastic body to deformation. For an elastic body with a single degree of freedom (DOF) (for example, stretching or compression of a rod), the stiffness is defined as where, F {\displaystyle F} is the force on the body.
The Rossby number (Ro), named for Carl-Gustav Arvid Rossby, is a dimensionless number used in describing fluid flow. The Rossby number is the ratio of inertial force to Coriolis force, terms and in the Navier–Stokes equations respectively. [1][2] It is commonly used in geophysical phenomena in the oceans and atmosphere, where it characterizes ...