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Selenium is found in metal sulfide ores, where it substitutes for sulfur. Commercially, selenium is produced as a byproduct in the refining of these ores. Minerals that are pure selenide or selenate compounds are rare. The chief commercial uses for selenium today are glassmaking and pigments. Selenium is a semiconductor and is used in photocells.
Analogous sulfoxide eliminations are generally harder to implement than selenoxide eliminations. Formation of the carbon–sulfur bond is usually accomplished with highly reactive sulfenyl chlorides, which must be prepared for immediate use. However, sulfoxides are more stable than the corresponding selenoxides, and elimination is usually ...
The sulfoxide in sulfur chemistry is represented in selenium chemistry by the selenoxides (formula RSe(O)R), which are intermediates in organic synthesis, as illustrated by the selenoxide elimination reaction. Consistent with trends indicated by the double bond rule, selenoketones, R(C=Se)R, and selenaldehydes, R(C=Se)H, are rarely observed.
[1] [2] [3] Selenium belongs with oxygen and sulfur to the group 16 elements or chalcogens, and similarities in chemistry are to be expected. Organoselenium compounds are found at trace levels in ambient waters, soils and sediments. [4] Selenium can exist with oxidation state −2, +2, +4, +6. Se(II) is the dominant form in organoselenium ...
Thiol with a blue highlighted sulfhydryl group.. In organic chemistry, a thiol (/ ˈ θ aɪ ɒ l /; [1] from Ancient Greek θεῖον (theion) 'sulfur' [2]), or thiol derivative, is any organosulfur compound of the form R−SH, where R represents an alkyl or other organic substituent.
Rubidium selenide is an inorganic compound composed of selenium and rubidium. It is a selenide with a chemical formula of Rb 2 Se. Rubidium selenide is used together with caesium selenide in photovoltaic cells .
Carbonyl selenide can be produced by treating selenium with carbon monoxide in the presence of amines. [3]It is used in organoselenium chemistry as a means of incorporating selenium into organic compounds, e.g. for the preparation of selenocarbamates (O-selenocarbamates R−O−C(=Se)−NR'R" and Se-selenocarbamates, R−Se−C(=O)−NR'R", where R is organyl and R' and R" are any group ...
Download as PDF; Printable version; ... or selenium dioxydifluoride is a chemical compound with the formula SeO 2 F 2.