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In chemistry, a condenser is the apparatus that cools hot vapors, causing them to condense into a liquid. Examples include the Liebig condenser, Graham condenser, and Allihn condenser. This is not to be confused with a condensation reaction which links two fragments into a single molecule by an addition reaction and an elimination reaction.
Defining equation SI unit Dimension Temperature gradient: No standard symbol K⋅m −1: ΘL −1: Thermal conduction rate, thermal current, thermal/heat flux, thermal power transfer P = / W ML 2 T −3: Thermal intensity I = / W⋅m −2
The simplest type of condenser is a straight tube, cooled only by the surrounding air. The tube is held in a vertical or oblique position, and the vapor is fed through the upper end. The heat of condensation is carried away by convection. The neck of the retort is a classical example of a straight tube condenser.
The Antoine equation [3] [4] is a pragmatic mathematical expression of the relation between the vapor pressure and the temperature of pure liquid or solid substances. It is obtained by curve-fitting and is adapted to the fact that vapor pressure is usually increasing and concave as a function of temperature. The basic form of the equation is:
An isochoric process is described by the equation Q = ΔU. It would be convenient to have a similar equation for isobaric processes. Substituting the second equation into the first yields = + = (+) The quantity U + pV is a state function so that it can be given a name.
The coefficients of Antoine's equation are normally given in mmHg—even today where the SI is recommended and pascals are preferred. The usage of the pre-SI units has only historic reasons and originates directly from Antoine's original publication. It is however easy to convert the parameters to different pressure and temperature units.
The heat transfer coefficient is the heat transferred per unit area per kelvin. Thus area is included in the equation as it represents the area over which the transfer of heat takes place. The areas for each flow will be different as they represent the contact area for each fluid side.
In thermochemistry, a thermochemical equation is a balanced chemical equation that represents the energy changes from a system to its surroundings. One such equation involves the enthalpy change, which is denoted with Δ H {\displaystyle \Delta H} In variable form, a thermochemical equation would appear similar to the following: