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Arsenic trisulfide is the inorganic compound with the formula As 2 S 3. It is a dark yellow solid that is insoluble in water. It is a dark yellow solid that is insoluble in water. It also occurs as the mineral orpiment (Latin: auripigmentum), which has been used as a pigment called King's yellow.
The Marsh test is a highly sensitive method in the detection of arsenic, especially useful in the field of forensic toxicology when arsenic was used as a poison. It was developed by the chemist James Marsh and first published in 1836. [1] The method continued to be used, with improvements, in forensic toxicology until the 1970s. [2]
Arsenic sulfide may refer to: Arsenic trisulfide , As 2 S 3 , the mineral orpiment Arsenic pentasulfide , As 2 S 5 , similar structure to phosphorus pentasulfide (β-P 2 S 5 )
In organic and organometallic chemistry, trisulfide is the functional group R-S-S-S-R. Examples include: Diallyl trisulfide; Dimethyl trisulfide; Trisulfane (hydrogen trisulfide) Some inorganic compounds are also named trisulfides to reflect their stoichiometry. Examples include: Antimony trisulfide; Arsenic trisulfide; Bismuth trisulfide ...
James Marsh (2 September 1794 – 21 June 1846) was a British chemist who invented the Marsh test for detecting arsenic. Born in Kent, he was working as a labourer in Woolwich in the late 1810s and early 1820s, before joining the Royal Artillery. [1] He was married to Mary, and had four children, two of whom died in infancy. [2]
Arsenic trioxide powder.. Compounds of arsenic resemble in some respects those of phosphorus which occupies the same group (column) of the periodic table.The most common oxidation states for arsenic are: −3 in the arsenides, which are alloy-like intermetallic compounds, +3 in the arsenites, and +5 in the arsenates and most organoarsenic compounds.
In its standard state arsine is a colorless, denser-than-air gas that is slightly soluble in water (2% at 20 °C) [1] and in many organic solvents as well. [citation needed] Arsine itself is odorless, [5] but it oxidizes in air and this creates a slight garlic or fish-like scent when the compound is present above 0.5 ppm. [6]
The International Agency for Research on Cancer (IARC) recognizes arsenic and inorganic arsenic compounds as group 1 carcinogens, and the EU lists arsenic trioxide, arsenic pentoxide, and arsenate salts as category 1 carcinogens. Arsenic is known to cause arsenicosis when present in drinking water, "the most common species being arsenate [HAsO ...