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Sodium peroxide is an inorganic compound with the formula Na 2 O 2.This yellowish solid is the product of sodium ignited in excess oxygen. [3] It is a strong base. This metal peroxide exists in several hydrates and peroxyhydrates including Na 2 O 2 ·2H 2 O 2 ·4H 2 O, Na 2 O 2 ·2H 2 O, Na 2 O 2 ·2H 2 O 2, and Na 2 O 2 ·8H 2 O. [4] The octahydrate, which is simple to prepare, is white, in ...
Sodium or lithium peroxides are preferred in space applications because of their lower molar mass and therefore higher oxygen yield per unit weight. [3] 2 Na 2 O 2 + 2 CO 2 → 2 Na 2 CO 3 + O 2. Alkali metal peroxides can be used for the synthesis of organic peroxides. One example is the conversion of benzoyl chloride with sodium peroxide to ...
Acid–base-catalysed hydrolyses are very common; one example is the hydrolysis of amides or esters. Their hydrolysis occurs when the nucleophile (a nucleus-seeking agent, e.g., water or hydroxyl ion) attacks the carbon of the carbonyl group of the ester or amide. In an aqueous base, hydroxyl ions are better nucleophiles than polar molecules ...
Sodium peroxide (Na 2 O 2) is used to oxidize the sample that becomes soluble in a diluted acid solution. This method allows complete dissolution of numerous refractory compounds like chromite , magnetite , ilmenite , rutile , and even silicon , carbides , alloys , noble metals and materials with high sulfide contents.
In addition to hydrogen peroxide, some other major classes of peroxides are: Peroxy acids, the peroxy derivatives of many familiar acids, examples being peroxymonosulfuric acid and peracetic acid, and their salts, one example of which is potassium peroxydisulfate. Main group peroxides, compounds with the linkage E−O−O−E (E = main group ...
Typical bleach activators are essentially N- and O-acyl compounds that form peroxyacids upon perhydrolysis (meaning hydrolysis by hydrogen peroxide from the bleach, persalts). For example, TAED produces in the wash liquor bleach-active peroxyacetic acid or from DOBA peroxydodecanoic acid. In all cases, the activator is chemically reacted ...
Diacyl peroxides are typically prepared by treating hydrogen peroxide with acid chlorides or acid anhydrides in the presence of base: [1] H 2 O 2 + 2 RCOCl → (RCO 2) 2 + 2 HCl H 2 O 2 + (RCO) 2 O → (RCO 2) 2 + H 2 O. The reaction competes with hydrolysis of the acylating agent but the hydroperoxide anion is a superior nucleophile relative ...
One example involves sodium perborate, a commercially important bleaching agent with the formula Na 2 [(HO) 2 B] 2 (OO) 2)]. It acts by hydrolysis to give a boron-hydroperoxide: [16] [(HO) 2 B] 2 (OO) 2) 2− + 2 H 2 O ⇌ 2 [(HO) 3 B(OOH)] −. This hydrogen peroxide then releases hydrogen peroxide: [(HO) 3 B(OOH)] − + H 2 O ⇌ B(OH) − 4 ...