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The heat capacity of an object is an amount of energy divided by a temperature change, which has the dimension L 2 ⋅M⋅T −2 ⋅Θ −1. Therefore, the SI unit J/K is equivalent to kilogram meter squared per second squared per kelvin (kg⋅m 2 ⋅s −2 ⋅K −1 ).
The measured heat energy released in an exothermic reaction is converted to ΔH⚬ in Joule per mole (formerly cal/mol). The standard enthalpy change Δ H ⚬ is essentially the enthalpy change when the stoichiometric coefficients in the reaction are considered as the amounts of reactants and products (in mole); usually, the initial and final ...
In theoretical physics, negative mass is a hypothetical type of exotic matter whose mass is of opposite sign to the mass of normal matter, e.g. −1 kg. [1] [2] Such matter would violate one or more energy conditions and exhibit strange properties such as the oppositely oriented acceleration for an applied force orientation.
Thus, a negative value of the change in free energy (G or A) is a necessary condition for a process to be spontaneous. This is the most useful form of the second law of thermodynamics in chemistry, where free-energy changes can be calculated from tabulated enthalpies of formation and standard molar entropies of reactants and products.
Since the molar heat capacity of a substance is the specific heat c times the molar mass of the substance M/N its numerical value is generally smaller than that of the specific heat. Paraffin wax , for example, has a specific heat of about 2500 J⋅K −1 ⋅kg −1 but a molar heat capacity of about 600 J⋅K −1 ⋅mol −1 .
An equivalent statement of the Dulong–Petit law in modern terms is that, regardless of the nature of the substance, the specific heat capacity c of a solid element (measured in joule per kelvin per kilogram) is equal to 3R/M, where R is the gas constant (measured in joule per kelvin per mole) and M is the molar mass (measured in kilogram per mole).
Thermodynamic work is one of the principal kinds of process by which a thermodynamic system can interact with and transfer energy to its surroundings. This results in externally measurable macroscopic forces on the system's surroundings, which can cause mechanical work, to lift a weight, for example, [1] or cause changes in electromagnetic, [2] [3] [4] or gravitational [5] variables.
The macroscopic energy equation for infinitesimal volume used in heat transfer analysis is [6] = +, ˙, where q is heat flux vector, −ρc p (∂T/∂t) is temporal change of internal energy (ρ is density, c p is specific heat capacity at constant pressure, T is temperature and t is time), and ˙ is the energy conversion to and from thermal ...