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[2] Like many metal sulfates, manganese sulfate forms a variety of hydrates: monohydrate, tetrahydrate, pentahydrate, and heptahydrate. All of these salts dissolve in water to give faintly pink solutions of the aquo complex [Mn(H 2 O) 6] 2+. The structure of MnSO 4 ·H 2 O has been determined by X-ray crystallography (see figure).
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
In Mn(CH 3) 2 (dmpe) 2, Mn(II) is low spin, which contrasts with the high spin character of its precursor, MnBr 2 (dmpe) 2 (dmpe = (CH 3) 2 PCH 2 CH 2 P(CH 3) 2). [38] Polyalkyl and polyaryl derivatives of manganese often exist in higher oxidation states, reflecting the electron-releasing properties of alkyl and aryl ligands.
Some hydroxides of non-metallic elements are soluble in water; they are not included in the following table. Examples cited by Baes and Mesmer (p. 413) include hydroxides of Gallium(III), Indium(III), Thallium(III), Arsenic(III), Antimony(III) and Bismuth(III). Most hydroxides of transition metals are classified as being "insoluble" in water.
Manganese(II,III) oxide is the chemical compound with formula Mn 3 O 4. Manganese is present in two oxidation states +2 and +3 and the formula is sometimes written as MnO·Mn 2 O 3. Mn 3 O 4 is found in nature as the mineral hausmannite.
Ammonium iron(II) sulfate, or Mohr's salt, is the inorganic compound with the formula (NH 4) 2 SO 4 ·Fe(SO 4)·6H 2 O.Containing two different cations, Fe 2+ and NH + 4, it is classified as a double salt of ferrous sulfate and ammonium sulfate.
A sulfite sulfate is a chemical compound that contains both sulfite and sulfate anions [SO 3] 2− [SO 4] 2−. These compounds were discovered in the 1980s as calcium and rare earth element salts. Minerals in this class were later discovered. Minerals may have sulfite as an essential component, or have it substituted for another anion as in ...
The crystal structure of manganese(II) sulfide is similar to that of sodium chloride.. The pink color of MnS likely results from poor coupling between the lowest energy unoccupied Mn orbitals, resulting in discrete states rather than a delocalized band.