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Martensite has a lower density than austenite, so that the martensitic transformation results in a relative change of volume. [4] Of considerably greater importance than the volume change is the shear strain, which has a magnitude of about 0.26 and which determines the shape of the plates of martensite. [5]
The metal is heated into the austenite region of the iron-cementite phase diagram and then quenched in a salt bath or other heat extraction medium that is between temperatures of 300–375 °C (572–707 °F). The metal is annealed in this temperature range until the austenite turns to bainite or ausferrite (bainitic ferrite + high-carbon ...
The iron-chromium phase diagram shows that up to about 13% Cr, the steel undergoes successive transformations upon cooling from the liquid phase from ferritic α phase to austenitic γ phase and back to α. When some carbon is present, and if cooling occurs quickly, some of the austenite will transform into martensite.
Below 912 °C (1,674 °F), iron has a body-centered cubic (bcc) crystal structure and is known as α-iron or ferrite. It is thermodynamically stable and a fairly soft metal. α-Fe can be subjected to pressures up to ca. 15 GPa before transforming into a high-pressure form termed ε-Fe discussed below.
Bainite is a plate-like microstructure that forms in steels at temperatures of 125–550 °C (depending on alloy content). [1] First described by E. S. Davenport and Edgar Bain, [2] [3] it is one of the products that may form when austenite (the face-centered cubic crystal structure of iron) is cooled past a temperature where it is no longer thermodynamically stable with respect to ferrite ...
Austenite is slightly undercooled when quenched below Eutectoid temperature. When given more time, stable microconstituents can form: ferrite and cementite. Coarse pearlite is produced when atoms diffuse rapidly after phases that form pearlite nucleate. This transformation is complete at the pearlite finish time (P f).