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Commercial reference electrodes consist of a glass or plastic tube electrode body. The electrode consists of a metallic silver wire (Ag (s)) coated with a thin layer of silver chloride (AgCl), either physically by dipping the wire in molten silver chloride, chemically by electroplating the wire in concentrated hydrochloric acid (HCl) [3] or electrochemically by oxidising the silver at an anode ...
Potentiometry passively measures the potential of a solution between two electrodes, affecting the solution very little in the process. One electrode is called the reference electrode and has a constant potential, while the other one is an indicator electrode whose potential changes with the sample's composition. Therefore, the difference in ...
The simplicity of construction meant that the electrode could be made small enough to be swallowed. Thin copper wires were attached to the electrode and one terminal on a pH meter. The subject's foot was placed in a saline solution. A calomel reference electrode was also placed in this solution and was connected to the other terminal on the ...
Portable, or field pH meters, are handheld pH meters that are used to take the pH of a sample in a field or production site. [19] In-line or in situ pH meters, also called pH analyzers, are used to measure pH continuously in a process, and can stand-alone, or be connected to a higher level information system for process control. [20]
The connection can be direct, through a narrow tube to reduce mixing, or through a salt bridge, depending on the other electrode and solution. This creates an ionically conductive path to the working electrode of interest. A reference electrode is an electrode that has a stable and well-known electrode potential.
The most common application of ion-selective glass electrodes is for the measurement of pH. The pH electrode is an example of a glass electrode that is sensitive to hydrogen ions. Glass electrodes play an important part in the instrumentation for chemical analysis, and physicochemical studies.
Reference electrodes generally used are hydrogen electrodes, calomel electrodes, and silver chloride electrodes. The indicator electrode forms an electrochemical half-cell with the interested ions in the test solution. The reference electrode forms the other half-cell. The overall electric potential is calculated as
Primary pH standard values are determined using a concentration cell with transference by measuring the potential difference between a hydrogen electrode and a standard electrode such as the silver chloride electrode. The pH of aqueous solutions can be measured with a glass electrode and a pH meter or a color-changing indicator.