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The Statue of Liberty, showing advanced patination; verdigris is responsible for the statue's iconic green colour.. Verdigris (/ ˈ v ɜːr d ɪ ɡ r iː (s)/) [1] is a common name for any of a variety of somewhat toxic [2] [3] [4] copper salts of acetic acid, which range in colour from green to a bluish-green depending on their chemical composition.
Bronze disease is an irreversible and nearly inexorable corrosion process that occurs when chlorides come into contact with bronze or other copper-bearing alloys. [1] It can occur as both a dark green coating, or as a much lighter whitish fuzzy or furry green coating. [1]
This type of patina is formed by corrosion, what elements the air might hold, residue from the wear of the carbon brush, and moisture; thus, the patina needs special conditions to work as intended. Patinas can also be found in woks or other metal baking dishes. The process of applying patinas to cookware is known as seasoning.
Protective elements for bronze fountains are particularly important, since water is one of the leading causes for alterations or corrosion in a bronze. [2] Bronze sculptures incorporated in fountains will need more layers of wax, because the spray of water will cause deterioration of the wax at a faster pace than would normally happen.
When built, the statue was reddish-brown and shiny, but within twenty years it had oxidized to its current green color through reactions with air, water and acidic pollution, forming a layer of verdigris which protects the copper from further corrosion. [120]
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Verdigris or Vert-de-Gris, is a blue-green, copper-based pigment. Its name comes from the natural pigments that form a patina on copper, bronze, and brass as it ages. [2] The most famous example is the green patina that formed on the Statue of Liberty in New York Harbor.
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