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Viscosity is a measure of a fluid's rate-dependent resistance to a change in shape or to movement of its neighboring portions relative to one another. [1] For liquids, it corresponds to the informal concept of thickness; for example, syrup has a higher viscosity than water. [2]
The viscosity of the sample is then calculated using the following equation: = ˙ where is the sample viscosity, and is the force applied to the sample to pull it apart. Much like the Meissner-type rheometer, the SER rheometer uses a set of two rollers to strain a sample at a given rate. [ 31 ]
In physics and chemistry, a non-Newtonian fluid is a fluid that does not follow Newton's law of viscosity, that is, it has variable viscosity dependent on stress. In particular, the viscosity of non-Newtonian fluids can change when subjected to force. Ketchup, for example
Any equation that makes explicit one of these transport coefficient in the conservation variables is called an equation of state. [9] Apart from its dependence of pressure and temperature, the second viscosity coefficient also depends on the process, that is to say, the second viscosity coefficient is not just a material property.
This functional relationship is described by a mathematical viscosity model called a constitutive equation which is usually far more complex than the defining equation of shear viscosity. One such complicating feature is the relation between the viscosity model for a pure fluid and the model for a fluid mixture which is called mixing rules.
Where: , , and are material coefficients: is the viscosity at zero shear rate (Pa.s), is the viscosity at infinite shear rate (Pa.s), is the characteristic time (s) and power index. The dynamics of fluid motions is an important area of physics, with many important and commercially significant applications.
A simple and widespread empirical correlation for liquid viscosity is a two-parameter exponential: = / This equation was first proposed in 1913, and is commonly known as the Andrade equation (named after British physicist Edward Andrade). It accurately describes many liquids over a range of temperatures.
Dynamic viscosity is a material property which describes the resistance of a fluid to shearing flows. It corresponds roughly to the intuitive notion of a fluid's 'thickness'. For instance, honey has a much higher viscosity than water. Viscosity is measured using a viscometer. Measured values span several orders of magnitude.