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Tetrafluoroethane (a haloalkane) is a colorless liquid that boils well below room temperature (as seen here) and can be extracted from common canned air canisters by simply inverting them during use. The haloalkanes (also known as halogenoalkanes or alkyl halides) are alkanes containing one or more halogen substituents. [1]
The Sandmeyer reaction is an example of a radical-nucleophilic aromatic substitution (S RN Ar). The radical mechanism of the Sandmeyer reaction is supported by the detection of biaryl byproducts. [8]
Haloarenes are different from haloalkanes because they exhibit many differences in methods of preparation and properties. The most important members are the aryl chlorides, but the class of compounds is so broad that there are many derivatives and applications.
The reaction is named after Cläre Hunsdiecker and her husband Heinz Hunsdiecker, whose work in the 1930s [5] [6] developed it into a general method. [1]The reaction was first demonstrated by Alexander Borodin in 1861 in his reports of the preparation of methyl bromide (CH 3 Br) from silver acetate (CH 3 CO 2 Ag).
The Darzens reaction (also known as the Darzens condensation or glycidic ester condensation) is the chemical reaction of a ketone or aldehyde with an α-haloester in the presence of a base to form an α,β-epoxy ester, also called a "glycidic ester".
1,2-Dichloro-1,1-difluoroethane (also R-132b or HCFC-132b) is a haloalkane and a hydrochlorofluorocarbon. It is an intermediate during the production of HFC-134a . [ 2 ] : Figure 7-2 According to a 2022 report by the WMO and other agencies, it has an ODP of 0.038 and a 100-year GWP of 332. [ 2 ] :
An example of the E1cB reaction mechanism in the degradation of a hemiketal under basic conditions. The E1cB elimination reaction is a type of elimination reaction which occurs under basic conditions, where the hydrogen to be removed is relatively acidic, while the leaving group (such as -OH or -OR) is a relatively poor one.
2-Chloro-1,1-difluoroethane (HCFC-142) is a haloalkane and a hydrochlorofluorocarbon. It is produced as a byproduct of the production of 1-chloro-1,1-difluoroethane (HCFC-142b). [1] According to a 2022 report by the WMO and other agencies, it has an ODP of 0.019 and a 100-year GWP of 189. [2]: Table A-5