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An anode ray (also positive ray or canal ray) is a beam of positive ions that is created by certain types of gas-discharge tubes. They were first observed in Crookes tubes during experiments by the German scientist Eugen Goldstein, in 1886. [1] Later work on anode rays by Wilhelm Wien and J. J. Thomson led to the development of mass spectrometry.
In the experiment, Ives and Stilwell used hydrogen discharge tubes as the source of canal rays which consisted primarily of positive H 2 + and H 3 + ions. (Free H + ions were present in too small an amount to be usable, since they quickly combined with H 2 molecules to form H 3 + ions.)
Wet electrons are produced when high-energy radiation, such as gamma rays, X-rays, or energetic particles, ionizes water molecules. This ionization results in the liberation of electrons, which, instead of remaining free, can become transiently localized due to induced polarization of the surrounding water molecules.
Crookes X-ray tube from around 1910 Another Crookes x-ray tube. The device attached to the neck of the tube (right) is an "osmotic softener". When the voltage applied to a Crookes tube is high enough, around 5,000 volts or greater, [16] it can accelerate the electrons to a high enough velocity to create X-rays when they hit the anode or the glass wall of the tube.
Eugen Goldstein (/ ˈ ɔɪ ɡ ən / OY-gən, German: [ˈɔʏɡeːn ˈɡɔlt.ʃtaɪn, ˈɔʏɡn̩-]; 5 September 1850 – 25 December 1930) was a German physicist.He was an early investigator of discharge tubes, the discoverer of anode rays or canal rays, later identified as positive ions in the gas phase including the hydrogen ion.
In water, the dimerization reaction of hydroxyl radicals can form hydrogen peroxide, while in saline systems the reaction of the hydroxyl radicals with chloride anions forms hypochlorite anions. The action of radiation upon underground water is responsible for the formation of hydrogen which is converted by bacteria into methane. [23] [24]
Rutherford determined that the only place this hydrogen could have come from was the nitrogen, and therefore nitrogen must contain hydrogen nuclei. He thus suggested that the hydrogen nucleus, which was known to have an atomic number of 1, was an elementary particle, which he decided must be the protons hypothesized by Eugen Goldstein (1886). 1919
By replenishing lost electrons with electrons from the splitting of water, photosystem II provides the electrons for all of photosynthesis to occur. The hydrogen ions (protons) generated by the oxidation of water help to create a proton gradient that is used by ATP synthase to generate ATP .