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An anode ray (also positive ray or canal ray) is a beam of positive ions that is created by certain types of gas-discharge tubes. They were first observed in Crookes tubes during experiments by the German scientist Eugen Goldstein, in 1886. [1] Later work on anode rays by Wilhelm Wien and J. J. Thomson led to the development of mass spectrometry.
Crookes X-ray tube from around 1910 Another Crookes x-ray tube. The device attached to the neck of the tube (right) is an "osmotic softener". When the voltage applied to a Crookes tube is high enough, around 5,000 volts or greater, [16] it can accelerate the electrons to a high enough velocity to create X-rays when they hit the anode or the glass wall of the tube.
Radiolysis is the dissociation of molecules by ionizing radiation.It is the cleavage of one or several chemical bonds resulting from exposure to high-energy flux.The radiation in this context is associated with ionizing radiation; radiolysis is therefore distinguished from, for example, photolysis of the Cl 2 molecule into two Cl-radicals, where (ultraviolet or visible spectrum) light is used.
When the electrons strike the shadow mask, they release their energy as heat and x-rays. If the electrons have too much energy due to an anode voltage that is too high for example, the shadow mask can warp due to the heat, which can also happen during the Lehr baking at ~435 °C of the frit seal between the faceplate and the funnel of the CRT.
Figure 1. Ives–Stilwell experiment (1938). "Canal rays" (a mixture of mostly H 2 + and H 3 + ions) were accelerated through perforated plates charged from 6,788 to 18,350 volts. The beam and its reflected image were simultaneously observed with the aid of a concave mirror offset 7° from the beam. [1] Figure 2.
As ionizing radiation moves through matter its energy is deposited through interactions with the electrons of the absorber. [1] The result of an interaction between the radiation and the absorbing species is removal of an electron from an atom or molecular bond to form radicals and excited species. The radical species then proceed to react with ...
Eugen Goldstein (/ ˈ ɔɪ ɡ ən / OY-gən, German: [ˈɔʏɡeːn ˈɡɔlt.ʃtaɪn, ˈɔʏɡn̩-]; 5 September 1850 – 25 December 1930) was a German physicist.He was an early investigator of discharge tubes, the discoverer of anode rays or canal rays, later identified as positive ions in the gas phase including the hydrogen ion.
Solvated electrons are involved in the reaction of alkali metals with water, even though the solvated electron has only a fleeting existence. [10] Below pH = 9.6 the hydrated electron reacts with the hydronium ion giving atomic hydrogen, which in turn can react with the hydrated electron giving hydroxide ion and usual molecular hydrogen H 2 .