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Nitrogen is the most critical element obtained by plants from the soil, to the exception of moist tropical forests where phosphorus is the limiting soil nutrient, [36] and nitrogen deficiency often limits plant growth. [37] Plants can use nitrogen as either the ammonium cation (NH 4 +) or the anion nitrate (NO 3 −).
Mineral ions cross plasma membranes by a chemiosmotic mechanism. Plants absorb minerals in ionic form: nitrate (NO 3 −), phosphate (HPO 4 −) and potassium ions (K +); all have difficulty crossing a charged plasma membrane. It has long been known plants expend energy to actively take up and concentrate mineral ions.
Plant nutrition is the study of the chemical elements and compounds necessary for plant growth and reproduction, plant metabolism and their external supply. In its absence the plant is unable to complete a normal life cycle, or that the element is part of some essential plant constituent or metabolite .
Nitrogen assimilation is the formation of organic nitrogen compounds like amino acids from inorganic nitrogen compounds present in the environment. Organisms like plants, fungi and certain bacteria that can fix nitrogen gas (N 2) depend on the ability to assimilate nitrate or ammonia for their needs.
If nitrate is absorbed, it is first reduced to nitrite ions and then ammonium ions for incorporation into amino acids, nucleic acids, and chlorophyll. In plants that have a symbiotic relationship with rhizobia, some nitrogen is assimilated in the form of ammonium ions directly from the nodules.
Nitrogen cycle. Nitrification is the biological oxidation of ammonia to nitrate via the intermediary nitrite.Nitrification is an important step in the nitrogen cycle in soil.The process of complete nitrification may occur through separate organisms [1] or entirely within one organism, as in comammox bacteria.
If the C:N ratio of the decomposing organic matter is above circa 30:1 then the decomposing microbes may absorb nitrogen in mineral form as, e. g., ammonium or nitrates. This mineral nitrogen is said to be immobilized. This may reduce the concentration of inorganic nitrogen in the soil and thus the nitrogen is not available to plants.
In the NO − 3 anion, the oxidation state of the central nitrogen atom is V (+5). This corresponds to the highest possible oxidation number of nitrogen. Nitrate is a potentially powerful oxidizer as evidenced by its explosive behaviour at high temperature when it is detonated in ammonium nitrate (NH 4 NO 3), or black powder, ignited by the shock wave of a primary explosive.