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Clathrate compound. A clathrate is a chemical substance consisting of a lattice that traps or contains molecules. The word clathrate is derived from the Latin clathratus (clatratus), meaning 'with bars, latticed '. [1] Most clathrate compounds are polymeric and completely envelop the guest molecule, but in modern usage clathrates also include ...
Methane clathrate block embedded in the sediment of hydrate ridge, off Oregon, USA. Clathrate hydrates, or gas hydrates, clathrates, or hydrates, are crystalline water-based solids physically resembling ice, in which small non-polar molecules (typically gases) or polar molecules with large hydrophobic moieties are trapped inside "cages" of hydrogen bonded, frozen water molecules.
Similar reactions can occur on the halogenated product, leading to replacement of additional hydrogen atoms by halogen atoms with dihalomethane, trihalomethane, and ultimately, tetrahalomethane structures, depending upon reaction conditions and the halogen-to-methane ratio. This reaction is commonly used with chlorine to produce dichloromethane ...
[6]: 2 Methane is a major source of water vapour in the stratosphere through oxidation; [7] and water vapour adds about 15% to methane's radiative forcing effect. [8] The global warming potential (GWP) for methane is about 84 in terms of its impact over a 20-year timeframe, and 28 in terms of its impact over a 100-year timeframe. [9] [10]
Chloromethane is produced commercially by treating methanol with hydrochloric acid or hydrogen chloride, according to the chemical equation: [5] CH 3 OH + HCl → CH 3 Cl + H 2 O. A smaller amount of chloromethane is produced by treating a mixture of methane with chlorine at elevated temperatures.
Methane clathrate (CH 4 ·5.75H 2 O) or (4CH 4 ·23H 2 O), also called methane hydrate, hydromethane, methane ice, fire ice, natural gas hydrate, or gas hydrate, is a solid clathrate compound (more specifically, a clathrate hydrate) in which a large amount of methane is trapped within a crystal structure of water, forming a solid similar to ice ...
The hydroxyl radical, •HO, is the neutral form of the hydroxide ion (HO –). Hydroxyl radicals are highly reactive and consequently short-lived; however, they form an important part of radical chemistry. Most notably hydroxyl radicals are produced from the decomposition of hydroperoxides (ROOH) or, in atmospheric chemistry, by the reaction ...
Clathrate gun hypothesis. Methane clathrate is released as gas into the surrounding water column or soils when ambient temperature increases. The clathrate gun hypothesis is a proposed explanation for the periods of rapid warming during the Quaternary. The hypothesis is that changes in fluxes in upper intermediate waters in the ocean caused ...