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Sodium bisulfite (or sodium bisulphite, sodium hydrogen sulfite) is a chemical mixture with the approximate chemical formula NaHSO 3. Sodium bisulfite is not a real compound, [ 2 ] but a mixture of salts that dissolve in water to give solutions composed of sodium and bisulfite ions.
The bisulfite ion (IUPAC-recommended nomenclature: hydrogensulfite) is the ion HSO − 3. Salts containing the HSO − 3 ion are also known as "sulfite lyes". [1] Sodium bisulfite is used interchangeably with sodium metabisulfite (Na 2 S 2 O 5). Sodium metabisulfite dissolves in water to give a solution of Na + HSO − 3. Na 2 S 2 O 5 + H 2 O ...
Chief among sulfite process byproducts are lignosulfonates, which find a wide variety of uses where a relatively inexpensive agent is needed to make a water dispersion of a water-insoluble material. Lignosulfonates are used in tanning leather, making concrete , drilling mud , drywall and so on.
Sodium bisulfate, also known as sodium hydrogen sulfate, [a] is the sodium salt of the bisulfate anion, with the molecular formula NaHSO 4. Sodium bisulfate is an acid salt formed by partial neutralization of sulfuric acid by an equivalent of sodium base, typically in the form of either sodium hydroxide (lye) or sodium chloride (table salt).
An alternative protocol uses a solution of iodate ion (for instance potassium iodate) to which an acidified solution (again with sulfuric acid) of sodium bisulfite is added. [3] In this protocol, iodide ion is generated by the following slow reaction between the iodate and bisulfite: IO − 3 + 3 HSO − 3 → I − + 3 HSO − 4
Sodium sulfite used industrial as a corrosion inhibitor/oxygen scavenger. Monoprotonation of sulfite gives HSO 3 −, which is called bisulfite. The sodium and potassium salts of bisulfite are not available, but solid and solutions of the approximate formula NaHSO 3 and KHSO 3 are widely marketed as sodium bisulfite and potassium bisulfite.
The sulfite ion is the conjugate base of bisulfite. Although its acid (sulfurous acid) is elusive, [1] its salts are widely used. Sulfites are substances that naturally occur in some foods and the human body. They are also used as regulated food additives. [2] When in food or drink, sulfites are often lumped together with sulfur dioxide. [3]
Hydroxysultaine is prepared industrially by the reaction of sodium bisulfite with epichlorohydrin to give the sodium salt (sodium 1-chloro-2-hydroxypropane sulfonate). [1] This is similar to the synthesis of isethionate, which is also used as a 'head-group' in surfactants.