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Chemistry Letters is a peer-reviewed scientific journal published by the Chemical Society of Japan. It specializes in the rapid publication of reviews and letters on all areas of chemistry. The editor-in-chief is Mitsuhiko Shionoya (University of Tokyo). According to the Journal Citation Reports, the journal has a 2014 impact factor of 1.23. [1]
After the active form of the ruthenium catalyst complex is generated from 1, acetophenone coordinates to the complex via its carbonyl oxygen and agostically via its ortho C-H bond (2). As in the Ru 0 proposed mechanism, this agostic interaction leads to the oxidative addition of the ortho C-H. Reductive elimination releases H 2 , which remains ...
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m-MTDATA - whose full name is 4,4',4"-Tris(N-3-methylphenyl-N-phenyl-amino) triphenylamine - is an organic molecule belonging to the class of starburst molecules, [3] often used as a material for the production of organic electronic devices.
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Concerted metalation-deprotonation (CMD) is a mechanistic pathway through which transition-metal catalyzed C–H activation reactions can take place. In a CMD pathway, the C–H bond of the substrate is cleaved and the new C–Metal bond forms through a single transition state. [1]
A recent review by Shenvi and coworkers, [8] proposed that the Mukaiyama hydration operates via the same principles as metal hydride hydrogen atom transfer (MH HAT), elucidated by Jack Halpern and Jack R. Norton in their studies on hydrogenation of anthracenes by syngas and Co 2 (CO) 8 [9] and the chemistry of vitamin B 12 mimics, [10 ...
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