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Hypophosphoric acid can be prepared by the reaction of red phosphorus with sodium chlorite at room temperature. [2]2 P + 2 NaClO 2 + 2 H 2 O → Na 2 H 2 P 2 O 6 + 2 HCl. A mixture of hypophosphoric acid, phosphorous acid (H 3 PO 3) and phosphoric acid (H 3 PO 4) is produced when white phosphorus oxidises in air when partially immersed in water.
A general formula for such cyclic compounds is [HPO 3] x where x = number of phosphoric units in the molecule. When metaphosphoric acids lose their hydrogens as H +, cyclic anions called metaphosphates are formed. An example of a compound with such an anion is sodium hexametaphosphate (Na 6 P 6 O 18), used as a sequestrant and a food additive.
Hypophosphorous acid was first prepared in 1816 by the French chemist Pierre Louis Dulong (1785–1838). [4]The acid is prepared industrially via a two step process: Firstly, elemental white phosphorus reacts with alkali and alkaline earth hydroxides to give an aqueous solution of hypophosphites:
In chemistry, phosphorus oxoacid (or phosphorus acid) is a generic name for any acid whose molecule consists of atoms of phosphorus, oxygen, and hydrogen. [1] There is a potentially infinite number of such compounds. Some of them are unstable and have not been isolated, but the derived anions and organic groups are present in stable salts and ...
An oxyacid, oxoacid, or ternary acid is an acid that contains oxygen. Specifically, it is a compound that contains hydrogen, oxygen, and at least one other element, with at least one hydrogen atom bonded to oxygen that can dissociate to produce the H + cation and the anion of the acid. [1]
Phosphoric acid (orthophosphoric acid, monophosphoric acid or phosphoric(V) acid) is a colorless, odorless phosphorus-containing solid, and inorganic compound with the chemical formula H 3 P O 4. It is commonly encountered as an 85% aqueous solution , which is a colourless, odourless, and non- volatile syrupy liquid.
The phosphate ion has a molar mass of 94.97 g/mol, and consists of a central phosphorus atom surrounded by four oxygen atoms in a tetrahedral arrangement. It is the conjugate base of the hydrogen phosphate ion H(PO 4) 2−, which in turn is the conjugate base of the dihydrogen phosphate ion H 2 (PO 4) −
Other important organic compounds that contain oxygen are: glycerol, formaldehyde, glutaraldehyde, citric acid, acetic anhydride, acetamide, etc. Epoxides are ethers in which the oxygen atom is part of a ring of three atoms. Oxygen reacts spontaneously with many organic compounds at or below room temperature in a process called autoxidation. [7]