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As an approximate rule, electron configurations are given by the Aufbau principle and the Madelung rule. However there are numerous exceptions; for example the lightest exception is chromium, which would be predicted to have the configuration 1s 2 2s 2 2p 6 3s 2 3p 6 3d 4 4s 2 , written as [Ar] 3d 4 4s 2 , but whose actual configuration given ...
In chemistry and atomic physics, an electron shell may be thought of as an orbit that electrons follow around an atom's nucleus. The closest shell to the nucleus is called the "1 shell" (also called the "K shell"), followed by the "2 shell" (or "L shell"), then the "3 shell" (or "M shell"), and so on further and further from the nucleus.
Note that these electron configurations are given for neutral atoms in the gas phase, which are not the same as the electron configurations for the same atoms in chemical environments. In many cases, multiple configurations are within a small range of energies and the small irregularities that arise in the d- and f-blocks are quite irrelevant ...
10 Ne 2 6 [Ne] 3s: 3p: 11 Na 1 - 12 Mg 2 - 13 Al 2 1 14 Si 2 2 15 P 2 3 16 S 2 4 17 Cl 2 5 18 Ar 2 6 [Ar] 4s: 3d: 4p: 19 K 1-- 20 Ca 2-- 21 Sc 2 1 - 22 Ti 2 2 - 23 V 2 3 - 24 Cr 1 5 - 25 Mn 2 5 - 26 Fe 2 6 - 27 Co 2 7 - 28 Ni 2 8 - 29 Cu 1 10 - 30 Zn 2 10 - 31 Ga 2 10 1 32 Ge 2 10 2 33 As 2 10 3 34 Se 2 10 4 35 Br 2 10 5 36 Kr 2 10 6 [Kr] 5s ...
Chromium and copper have electron configurations [Ar] 3d 5 4s 1 and [Ar] 3d 10 4s 1 respectively, i.e. one electron has passed from the 4s-orbital to a 3d-orbital to generate a half-filled or filled subshell. In this case, the usual explanation is that "half-filled or completely filled subshells are particularly stable arrangements of electrons".
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