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Chlorine can be manufactured by the electrolysis of a sodium chloride solution (), which is known as the Chloralkali process.The production of chlorine results in the co-products caustic soda (sodium hydroxide, NaOH) and hydrogen gas (H 2).
A gas regulator attached to a nitrogen cylinder. Industrial gases are the gaseous materials that are manufactured for use in industry.The principal gases provided are nitrogen, oxygen, carbon dioxide, argon, hydrogen, helium and acetylene, although many other gases and mixtures are also available in gas cylinders.
The chloralkali process (also chlor-alkali and chlor alkali) is an industrial process for the electrolysis of sodium chloride (NaCl) solutions. It is the technology used to produce chlorine and sodium hydroxide (caustic soda), [1] which are commodity chemicals required by industry.
However, the kinetics of this reaction are unfavorable, and there is also a bubble overpotential effect to consider, so that electrolysis of aqueous chloride solutions evolves chlorine gas and not oxygen gas, a fact that is very useful for the industrial production of chlorine. [45]
The process is also used to prepare the pentahydrate NaOCl·5H 2 O for industrial and laboratory use. In a typical process, chlorine gas is added to a 45–48% NaOH solution. Some of the sodium chloride precipitates and is removed by filtration, and the pentahydrate is then obtained by cooling the filtrate to 12 °C. [8]
The solution travels to a tank that separates the hydrogen gas based on its low density. [1] Only water and sodium chloride are used. The simplified chemical reaction is: NaCl + H 2 O + energy → NaOCl + H 2 [citation needed] That is, energy is added to sodium chloride (table salt) in water, producing sodium hypochlorite and hydrogen gas.
It is an important industrial chemical chiefly used to produce the polymer polyvinyl chloride (PVC). Vinyl chloride is a colourless flammable gas that has a sweet odor and is carcinogenic . Vinyl chloride monomer is among the top twenty largest petrochemicals ( petroleum -derived chemicals) in world production. [ 2 ]
In chemistry, oxychlorination is a process for generating the equivalent of chlorine gas (Cl 2) from hydrogen chloride and oxygen. [1] This process is attractive industrially because hydrogen chloride is less expensive than chlorine. [2]
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