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  2. Buchner ring expansion - Wikipedia

    en.wikipedia.org/wiki/Buchner_ring_expansion

    The Buchner ring expansion is a two-step organic C-C bond forming reaction used to access 7-membered rings. The first step involves formation of a carbene from ethyl diazoacetate, which cyclopropanates an aromatic ring. The ring expansion occurs in the second step, with an electrocyclic reaction opening the cyclopropane ring to form the 7 ...

  3. Ring expansion and contraction - Wikipedia

    en.wikipedia.org/wiki/Ring_expansion_and_contraction

    A common method for expanding a ring involves opening cyclopropane-containing bicyclic intermediate. The strategy can start with a Simmons-Smith-like cyclopropanation of a cyclic alkene. [3] A related cyclopropane-based ring expansion is the Buchner ring expansion. The Buchner ring expansion is used to convert arenes to cycloheptatrienes. The ...

  4. Puzzle solutions for Friday, Sept. 27

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    Find answers to the latest online sudoku and crossword puzzles that were published in USA TODAY Network's local newspapers. Puzzle solutions for Friday, Sept. 27 Skip to main content

  5. Danheiser benzannulation - Wikipedia

    en.wikipedia.org/wiki/Danheiser_Benzannulation

    This benzannulation reaction creates previously unaccessed aromatic substitution patterns. A variety of substituted aromatic rings can be prepared using this method including: phenols, naphthalenes, benzofurans, benzothiophenes, indoles, and carbazoles. [2] Scheme 2:Danheiser Benzannulation Reaction with an α-Diazo Ketone(X= OR, SR, NR2)

  6. NYT Connections Sports Edition Today: Hints and Answers for ...

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    Those of us word game addicts who already play Wordle, Connections, Strands and the Mini Crossword now have Connections Sports Edition to add to the mix. So, if you're looking for some hints and ...

  7. Today's Wordle Hint, Answer for #1335 on Thursday, February ...

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    Today's Wordle Answer for #1335 on Thursday, February 13, 2025. Today's Wordle answer on Thursday, February 13, 2025, is RUMBA. How'd you do? Up Next:

  8. Buchner Ring - Wikipedia

    en.wikipedia.org/?title=Buchner_Ring&redirect=no

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  9. Metal-catalyzed σ-bond rearrangement - Wikipedia

    en.wikipedia.org/wiki/Metal-catalyzed_σ-bond...

    The metal ion-catalyzed σ-bond rearrangement is a collection of chemical reactions that occur with highly strained organic compounds are treated with metal ions like Ag +, Rh(I), or Pd(II) based reagents.