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Internal energy: The energy contained within a body of matter or radiation, excluding the potential energy of the whole system, and excluding the kinetic energy of the system moving as a whole. Heat : Energy in transfer between a system and its surroundings by mechanisms other than thermodynamic work and transfer of matter.
Thermodynamic work is one of the principal kinds of process by which a thermodynamic system can interact with and transfer energy to its surroundings. This results in externally measurable macroscopic forces on the system's surroundings, which can cause mechanical work, to lift a weight, for example, [1] or cause changes in electromagnetic, [2] [3] [4] or gravitational [5] variables.
In thermodynamics, the Helmholtz free energy (or Helmholtz energy) is a thermodynamic potential that measures the useful work obtainable from a closed thermodynamic system at a constant temperature . The change in the Helmholtz energy during a process is equal to the maximum amount of work that the system can perform in a thermodynamic process ...
When designing a heat engine, the goal is to have the system produce and deliver work output. The source of energy in a heat engine, is a heat input. If the volume compresses (ΔV = final volume − initial volume < 0), then W < 0. That is, during isobaric compression the gas does negative work, or the environment does positive work. Restated ...
Ratio of thermal to rest mass-energy of each molecule: ... W = work done by engine; Q H = heat energy in higher temperature reservoir;
For a heat engine, thermal efficiency is the ratio of the net work output to the heat input; in the case of a heat pump, thermal efficiency (known as the coefficient of performance or COP) is the ratio of net heat output (for heating), or the net heat removed (for cooling) to the energy input (external work). The efficiency of a heat engine is ...
Energy transfer is considered as work done by the system only. Isothermal : The process is at a constant temperature during that part of the cycle (=, =). Energy transfer is considered as heat removed from or work done by the system.
The free energy is the portion of any first-law energy that is available to perform thermodynamic work at constant temperature, i.e., work mediated by thermal energy. Free energy is subject to irreversible loss in the course of such work. [ 1 ]