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The law also defines the internal energy of a system, an extensive property for taking account of the balance of heat and work in the system. Energy cannot be created or destroyed, but it can be transformed from one form to another. In an isolated system the sum of all forms of energy is constant.
Because it expresses conservation of total energy, this is sometimes referred to as the energy balance equation of continuous media. The first law is used to derive the non-conservation form of the Navier–Stokes equations. [3]
Just as with the internal energy version of the fundamental equation, the chain rule can be used on the above equations to find k+2 equations of state with respect to the particular potential. If Φ is a thermodynamic potential, then the fundamental equation may be expressed as:
Quantity (common name/s) (Common) symbol/s Defining equation SI unit Dimension Temperature gradient: No standard symbol K⋅m −1: ΘL −1: Thermal conduction rate, thermal current, thermal/heat flux, thermal power transfer
The energy balance is Δ E = + 4 + 4 − 5 − 3 = 0 {\displaystyle \Delta E=+4+4-5-3=0} Note that energy added to the system is counted as positive and energy leaving the system is counted as negative and the summation is zero as expected for a complete cycle that returns the system to its original state.
The compressible Euler equations consist of equations for conservation of mass, balance of momentum, and balance of energy, together with a suitable constitutive equation for the specific energy density of the fluid. Historically, only the equations of conservation of mass and balance of momentum were derived by Euler.
In thermochemistry, a thermochemical equation is a balanced chemical equation that represents the energy changes from a system to its surroundings. One such equation involves the enthalpy change, which is denoted with Δ H {\displaystyle \Delta H} In variable form, a thermochemical equation would appear similar to the following:
In environmental monitoring, the term budget calculations is used to describe mass balance equations where they are used to evaluate the monitoring data (comparing input and output, etc.). In biology, the dynamic energy budget theory for metabolic organisation makes explicit use of mass and energy balance.