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Hydrazine is an inorganic compound with the chemical formula N 2 H 4.It is a simple pnictogen hydride, and is a colourless flammable liquid with an ammonia-like odour.Hydrazine is highly hazardous unless handled in solution as, for example, hydrazine hydrate (N 2 H 4 ·xH 2 O).
Hydrazines (R 2 N−NR 2) are a class of chemical compounds with two nitrogen atoms linked via a covalent bond and which carry from one up to four alkyl or aryl substituents. . Hydrazines can be considered as derivatives of the inorganic hydrazine (H 2 N−NH 2), in which one or more hydrogen atoms have been replaced by hydrocarbon grou
There are various methods to synthesize aryl azides. One such method would be to set use react aniline with sodium nitrite (NaNO 2) and hydrazine hydrate in the presence of acetic acid. [2] This reaction will give moderate to good yield of the desired aryl azide. The best solvent for this reaction is dichloromethane.
When derived from hydrazine itself, hydrazones condense with a second equivalent of a carbonyl to give azines: [11] R 2 C=N−NH 2 + R 2 C=O → R 2 C=N−N=CR 2 + H 2 O. Hydrazones are intermediates in the Wolff–Kishner reduction. Hydrazones are reactants in hydrazone iodination, the Shapiro reaction, and the Bamford–Stevens reaction to ...
Ketazines are also important intermediates in the industrial production of hydrazine hydrate by the peroxide process. [3] In the presence of an oxidant, ammonia and ketones react to give hydrazine via ketazine: 2 Me(Et)C=O + 2 NH 3 + H 2 O 2 → Me(Et)C=NN=C(Et)Me + 2 H 2 O. The ketazine can be hydrolyzed to the hydrazine and regenerate the ketone:
Acetone hydrazone can be produced on large scale by reaction of acetone azine with hydrazine, a more convenient reaction than direct reaction of acetone and hydrazine. [3] Likewise, it is susceptible to disproportionation to revert to acetone azine and hydrazine, especially in the presence of water.
Hydrazine sulfate, more properly hydrazinium hydrogensulfate, is a salt of the cation hydrazinium and the anion bisulfate (hydrogensulfate), with the formula N 2 H 6 SO 4 or more properly [N 2 H 5] + [HSO 4] −.
Formylhydrazine is a chemical compound with the molecular formula CH 4 N 2 O and it has a mass of 60 g/mol. It is also known as formic acid hydrazide, hydrazinecarboxaldehyde, formohydrazide, or formic hydrazide.