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Phosphorus pentoxide crystallizes in at least four forms or polymorphs.The most familiar one, a metastable form [1] (shown in the figure), comprises molecules of P 4 O 10.Weak van der Waals forces hold these molecules together in a hexagonal lattice (However, in spite of the high symmetry of the molecules, the crystal packing is not a close packing [2]).
A complex is formed from two equivalents of the conjugate base of DEHPA and one uranyl ion. [6] Complexes of the formula (UO 2) 2 [(O 2 P(OR) 2] 4 also form, and at high concentrations of uranium, polymeric complexes may form. [5] The extractability of Fe 3+ is similar to that of uranium, so it must be reduced to Fe 2+ before the extraction. [5]
Unprocessed phosphate rock has a concentration of 1.7–8.7% phosphorus by mass (4–20% phosphorus pentoxide). By comparison, the Earth's crust contains 0.1% phosphorus by mass, [84] and vegetation 0.03–0.2%. [85] Although quadrillions of tons of phosphorus exist in the Earth's crust, [86] these are currently not economically extractable.
Phosphorus oxide can refer to: Phosphorus pentoxide (phosphorus(V) oxide, phosphoric anhydride), P 2 O 5; Phosphorus trioxide (phosphorus(III) oxide, phosphorous anhydride), P 2 O 3; Phosphorus tetroxide, P 2 O 4; Several other, less common, oxides of phosphorus, including P 4 O 7, P 4 O 9, and P 2 O 6; Gases: Phosphorus monoxide, PO ...
Phosphoryl chloride (commonly called phosphorus oxychloride) is a colourless liquid with the formula P O Cl 3. It hydrolyses in moist air releasing phosphoric acid and fumes of hydrogen chloride . It is manufactured industrially on a large scale from phosphorus trichloride and oxygen or phosphorus pentoxide . [ 4 ]
Phosphine (IUPAC name: phosphane) is a colorless, flammable, highly toxic compound with the chemical formula P H 3, classed as a pnictogen hydride.Pure phosphine is odorless, but technical grade samples have a highly unpleasant odor like rotting fish, due to the presence of substituted phosphine and diphosphane (P 2 H 4).
Elemental phosphorus is distilled out of the furnace and burned with air to produce high-purity phosphorus pentoxide, which is dissolved in water to make phosphoric acid. [22] The thermal process produces phosphoric acid with a very high concentration of P 2 O 5 (about 85%) and a low level of impurities.
Phosphorus pentoxide is a more complex molecular oxide with a deceptive name, the real formula being P 4 O 10. Tetroxides are rare, with a few more common examples being ruthenium tetroxide , osmium tetroxide , and xenon tetroxide .