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  2. Chirality (physics) - Wikipedia

    en.wikipedia.org/wiki/Chirality_(physics)

    The chiral symmetry transformation can be divided into a component that treats the left-handed and the right-handed parts equally, known as vector symmetry, and a component that actually treats them differently, known as axial symmetry. [2] (cf. Current algebra.) A scalar field model encoding chiral symmetry and its breaking is the chiral model.

  3. Absolute configuration - Wikipedia

    en.wikipedia.org/wiki/Absolute_configuration

    are arranged around the chiral center carbon atom. With the hydrogen atom away from the viewer, if the arrangement of the CO→R→N groups around the carbon atom as center is counter-clockwise, then it is the L form. [14] If the arrangement is clockwise, it is the D form. As usual, if the molecule itself is oriented differently, for example ...

  4. Chirality (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Chirality_(chemistry)

    Many chiral molecules have point chirality, namely a single chiral stereogenic center that coincides with an atom. This stereogenic center usually has four or more bonds to different groups, and may be carbon (as in many biological molecules), phosphorus (as in many organophosphates), silicon, or a metal (as in many chiral coordination compounds).

  5. Chirality - Wikipedia

    en.wikipedia.org/wiki/Chirality

    Chirality (/ k aɪ ˈ r æ l ɪ t i /) is a property of asymmetry important in several branches of science. The word chirality is derived from the Greek χείρ (kheir), "hand", a familiar chiral object. An object or a system is chiral if it is distinguishable from its mirror image; that is, it cannot be superposed (not to be confused with ...

  6. Molecular symmetry - Wikipedia

    en.wikipedia.org/wiki/Molecular_symmetry

    Center of symmetry or inversion center, abbreviated i. A molecule has a center of symmetry when, for any atom in the molecule, an identical atom exists diametrically opposite this center an equal distance from it. In other words, a molecule has a center of symmetry when the points (x,y,z) and (−x,−y,−z) of the molecule always look identical.

  7. Stereocenter - Wikipedia

    en.wikipedia.org/wiki/Stereocenter

    A chirality center (chiral center) is a type of stereocenter. A chirality center is defined as an atom holding a set of four different ligands (atoms or groups of atoms) in a spatial arrangement which is non-superposable on its mirror image. Chirality centers must be sp 3 hybridized, meaning that a chirality center can only have single bonds. [5]

  8. Tetrahedral molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Tetrahedral_molecular_geometry

    In a tetrahedral molecular geometry, a central atom is located at the center with four substituents that are located at the corners of a tetrahedron. The bond angles are arccos (− ⁠ 1 / 3 ⁠ ) = 109.4712206...° ≈ 109.5° when all four substituents are the same, as in methane ( CH 4 ) [ 1 ] [ 2 ] as well as its heavier analogues .

  9. Electron configuration - Wikipedia

    en.wikipedia.org/wiki/Electron_configuration

    The molecular orbitals are labelled according to their symmetry, [e] rather than the atomic orbital labels used for atoms and monatomic ions; hence, the electron configuration of the dioxygen molecule, O 2, is written 1σ g 2 1σ u 2 2σ g 2 2σ u 2 3σ g 2 1π u 4 1π g 2, [39] [40] or equivalently 1σ g 2 1σ u 2 2σ g 2 2σ u 2 1π u 4 3σ g ...

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