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The Van Slyke determination is a chemical test for the determination of amino acids containing a primary amine group. It is named after the biochemist Donald Dexter Van Slyke (1883-1971). [1] One of Van Slyke's first professional achievements was the quantification of amino acids by the Van Slyke determination reaction. [2]
Donald Dexter Van Slyke (March 29, 1883 – May 4, 1971), nicknamed Van, was a Dutch American biochemist. His achievements included the publication of 317 journal articles and 5 books, [ 1 ] as well as numerous awards, among them the National Medal of Science and the first AMA Scientific Achievement Award . [ 1 ]
By contrast, at almost the same time, Donald Van Slyke and G. E. Cullen [79] treated the binding step as an irreversible reaction. The Briggs–Haldane equation was of the same algebraic form as both of the earlier equations, but their derivation is based on the quasi- steady state approximation, which is the concentration of intermediate ...
Buffer capacity falls to 33% of the maximum value at pH = pK a ± 1, to 10% at pH = pK a ± 1.5 and to 1% at pH = pK a ± 2. For this reason the most useful range is approximately p K a ± 1. When choosing a buffer for use at a specific pH, it should have a p K a value as close as possible to that pH.
With nitrous acid, one obtains glycolic acid (van Slyke determination). With methyl iodide, the amine becomes quaternized to give trimethylglycine, a natural product: H 3 N + CH 2 COO − + 3 CH 3 I → (CH 3) 3 N + CH 2 COO − + 3 HI. Glycine condenses with itself to give peptides, beginning with the formation of glycylglycine: [34] 2 H 3 N ...
From May 2011 to October 2012, if you bought shares in companies when Peter B. Henry joined the board, and sold them when he left, you would have a 21.9 percent return on your investment, compared to a 9.7 percent return from the S&P 500.
Stephen Smale (born July 15, 1930) is an American mathematician, known for his research in topology, dynamical systems and mathematical economics.He was awarded the Fields Medal in 1966 [2] and spent more than three decades on the mathematics faculty of the University of California, Berkeley (1960–1961 and 1964–1995), where he currently is Professor Emeritus, with research interests in ...
Childress and Reid met in 1986 as assistant coaches at Northern Arizona University, where Reid drove around Flagstaff in a Volkswagen van from the 1960s with a stick shift and weathered brown paint.