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UNIFAC uses the functional groups present on the molecules that make up the liquid mixture to calculate activity coefficients. By using interactions for each of the functional groups present on the molecules, as well as some binary interaction coefficients, the activity of each of the solutions can be calculated.
Vieta's formulas are frequently used with polynomials with coefficients in any integral domain R. Then, the quotients a i / a n {\displaystyle a_{i}/a_{n}} belong to the field of fractions of R (and possibly are in R itself if a n {\displaystyle a_{n}} happens to be invertible in R ) and the roots r i {\displaystyle r_{i}} are taken in an ...
The Davies equation is an empirical extension of Debye–Hückel theory which can be used to calculate activity coefficients of electrolyte solutions at relatively high concentrations at 25 °C. The equation, originally published in 1938, [ 1 ] was refined by fitting to experimental data.
Layers of Pascal's pyramid derived from coefficients in an upside-down ternary plot of the terms in the expansions of the powers of a trinomial – the number of terms is clearly a triangular number. In mathematics, a trinomial expansion is the expansion of a power of a sum of three terms into monomials. The expansion is given by
A chemical equation is the symbolic representation of a chemical reaction in the form of symbols and chemical formulas.The reactant entities are given on the left-hand side and the product entities are on the right-hand side with a plus sign between the entities in both the reactants and the products, and an arrow that points towards the products to show the direction of the reaction. [1]
In chemistry, molecularity is the number of molecules that come together to react in an elementary (single-step) reaction [1] and is equal to the sum of stoichiometric coefficients of reactants in the elementary reaction with effective collision (sufficient energy) and correct orientation. [2]
They can be used to calculate mixed ion activity coefficients and water activities in solutions of high ionic strength for which the Debye–Hückel theory is no longer adequate. They are more rigorous than the equations of specific ion interaction theory (SIT theory), but Pitzer parameters are more difficult to determine experimentally than ...
This second form has advantages in computation cost and accuracy: it avoids evaluation of (); the work to compute each term in the denominator / has already been done in computing (/ ()) and so computing the sum in the denominator costs only addition operations; for evaluation points which are close to one of the nodes , catastrophic ...