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Phosphorus sulfides comprise a family of inorganic compounds containing only phosphorus and sulfur.These compounds have the formula P 4 S n with n ≤ 10. Two are of commercial significance, phosphorus pentasulfide (P 4 S 10), which is made on a kiloton scale for the production of other organosulfur compounds, and phosphorus sesquisulfide (P 4 S 3), used in the production of "strike anywhere ...
Fibrous red phosphorus is another crystalline form of red phosphorus. [7] It is obtained along with violet phosphorus when red phosphorus is sublimed in vacuum in the presence of iodine. [21] It is structurally similar to violet phosphorus. However, in fibrous red phosphorus, phosphorus chains lie parallel instead of orthogonal, unlike violet ...
Phosphorus has several allotropes that exhibit strikingly diverse properties. [11] The two most common allotropes are white phosphorus and red phosphorus. [12] For both pure and applied uses, the most important allotrope is white phosphorus, often abbreviated WP. White phosphorus is a soft, waxy molecular solid composed of P 4 tetrahedra. This P
White (in black-and-white): The mix of zinc cadmium sulfide and zinc sulfide silver, the ZnS:Ag + (Zn,Cd)S:Ag is the white P4 phosphor used in black and white television CRTs. Mixes of yellow and blue phosphors are usual. Mixes of red, green and blue, or a single white phosphor, can also be encountered.
With the addition of a grit such as boron carbide (in a modified formulation given as 70% KClO 3, 19% red phosphorus, 3% sulfur, 3% chalk, and 5% boron carbide by weight), Armstrong's mixture has been considered for use in firearm primers. [5] This use as primer for artillery propellants may have been Armstrong's original purpose. [6]
White phosphorus, yellow phosphorus or simply tetraphosphorus (P 4) exists as molecules of four phosphorus atoms in a tetrahedral structure, joined by six phosphorus—phosphorus single bonds. [1] The free P 4 molecule in the gas phase has a P-P bond length of r g = 2.1994(3) Å as was determined by gas electron diffraction . [ 2 ]
Phosphorus pentasulfide is the inorganic compound with the formula P 2 S 5 or P 4 S 10 . This yellow solid is the one of two phosphorus sulfides of commercial value. Samples often appear greenish-gray due to impurities. It is soluble in carbon disulfide but reacts with many other solvents such as alcohols, DMSO, and DMF.
There are many ways to prepare phosphide compounds. One common way involves heating a metal and red phosphorus (P) under inert atmospheric conditions or vacuum. In principle, all metal phosphides and polyphosphides can be synthesized from elemental phosphorus and the respective metal element in stoichiometric forms.