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These identities are useful whenever expressions involving trigonometric functions need to be simplified. An important application is the integration of non-trigonometric functions: a common technique involves first using the substitution rule with a trigonometric function, and then simplifying the resulting integral with a trigonometric identity.
In this case, an expression involving a radical function is replaced with a trigonometric one. Trigonometric identities may help simplify the answer. [1] [2] Like other methods of integration by substitution, when evaluating a definite integral, it may be simpler to completely deduce the antiderivative before applying the boundaries of integration.
The substitution is described in most integral calculus textbooks since the late 19th century, usually without any special name. [5] It is known in Russia as the universal trigonometric substitution, [6] and also known by variant names such as half-tangent substitution or half-angle substitution.
Substitution reactions are of prime importance in organic chemistry. Substitution reactions in organic chemistry are classified either as electrophilic or nucleophilic depending upon the reagent involved, whether a reactive intermediate involved in the reaction is a carbocation, a carbanion or a free radical, and whether the substrate is ...
The rules apply when the nucleophile can attack the bond in question in an ideal angle. These angles are 180° (Walden inversion) for exo-tet reactions, 109° (Bürgi–Dunitz angle) for exo-trig reaction and 120° for endo-dig reactions. Angles for nucleophilic attack on alkynes were reviewed and redefined recently. [4]
Using Euler's formula, any trigonometric function may be written in terms of complex exponential functions, namely and and then integrated. This technique is often simpler and faster than using trigonometric identities or integration by parts , and is sufficiently powerful to integrate any rational expression involving trigonometric functions.