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Iodoform stored in an ampoule. Iodoform (also known as triiodomethane) is the organoiodine compound with the chemical formula C H I 3.It is a pale yellow, crystalline, volatile substance, with a penetrating and distinctive odor (in older chemistry texts, the smell is sometimes referred to as that of hospitals, where the compound is still commonly used) and, analogous to chloroform, sweetish taste.
In chemistry, the haloform reaction (also referred to as the Lieben haloform reaction) is a chemical reaction in which a haloform (CHX 3, where X is a halogen) is produced by the exhaustive halogenation of an acetyl group (R−C(=O)CH 3, where R can be either a hydrogen atom, an alkyl or an aryl group), in the presence of a base.
The overall reaction is thus: I − 3 + 2 S 2 O 2− 3 → S 4 O 2− 6 + 3 I − (E reaction = +0.46 V) For simplicity, the equations will usually be written in terms of aqueous molecular iodine rather than the triiodide ion, as the iodide ion did not participate in the reaction in terms of mole ratio analysis.
Given the large size of the iodide anion and iodine's weak oxidising power, high oxidation states are difficult to achieve in binary iodides, the maximum known being in the pentaiodides of niobium, tantalum, and protactinium. Iodides can be made by reaction of an element or its oxide, hydroxide, or carbonate with hydroiodic acid, and then ...
Algar–Flynn–Oyamada reaction; Alkylimino-de-oxo-bisubstitution; Alkyne trimerisation; Alkyne zipper reaction; Allan–Robinson reaction; Allylic rearrangement; Amadori rearrangement; Amine alkylation; Angeli–Rimini reaction; Andrussov oxidation; Appel reaction; Arbuzov reaction, Arbusow reaction; Arens–Van Dorp synthesis, Isler ...
The iodide anion is a good nucleophile and will displace chloride, tosylate, bromide and other leaving groups, as in the Finkelstein reaction. Alcohols can be converted to the corresponding iodides using phosphorus triiodide. Illustrative is the conversion of methanol to iodomethane: [15] PI 3 + 3 CH 3 OH → 3 CH 3 I + "H 3 PO 3 "
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Iodomethane can also be prepared by the reaction of methanol with aqueous hydrogen iodide: CH 3 OH + HI → CH 3 I + H 2 O. The generated iodomethane can be distilled from the reaction mixture. Iodomethane may also be prepared by treating iodoform with potassium hydroxide and dimethyl sulfate under 95% ethanol. [7]