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Alligation is an old and practical method of solving arithmetic problems related to mixtures of ingredients. There are two types of alligation: alligation medial , used to find the quantity of a mixture given the quantities of its ingredients, and alligation alternate , used to find the amount of each ingredient needed to make a mixture of a ...
In crystallography, materials science and metallurgy, Vegard's law is an empirical finding (heuristic approach) resembling the rule of mixtures.In 1921, Lars Vegard discovered that the lattice parameter of a solid solution of two constituents is approximately a weighted mean of the two constituents' lattice parameters at the same temperature: [1] [2]
The Wilke mixing rule is capable of describing the correct viscosity behavior of gas mixtures showing a nonlinear and non-monotonical behavior, or showing a characteristic bump shape, when the viscosity is plotted versus mass density at critical temperature, for mixtures containing molecules of very different sizes.
A vapor can exist in equilibrium with a liquid (or solid), in which case the gas pressure equals the vapor pressure of the liquid (or solid). A supercritical fluid (SCF) is a gas whose temperature and pressure are above the critical temperature and critical pressure respectively. In this state, the distinction between liquid and gas disappears.
It can be used to determine the fraction of liquid and solid phases for a given binary composition and temperature that is between the liquidus and solidus line. [1] In an alloy or a mixture with two phases, α and β, which themselves contain two elements, A and B, the lever rule states that the mass fraction of the α phase is
Hume-Rothery rules, named after William Hume-Rothery, are a set of basic rules that describe the conditions under which an element could dissolve in a metal, forming a solid solution. There are two sets of rules; one refers to substitutional solid solutions, and the other refers to interstitial solid solutions.
The commonly known phases solid, liquid and vapor are separated by phase boundaries, i.e. pressure–temperature combinations where two phases can coexist. At the triple point, all three phases can coexist. However, the liquid–vapor boundary terminates in an endpoint at some critical temperature T c and critical pressure p c. This is the ...
The solidus temperature specifies the temperature below which a material is completely solid, [2] and the minimum temperature at which a melt can co-exist with crystals in thermodynamic equilibrium. Liquidus and solidus are mostly used for impure substances (mixtures) such as glasses , metal alloys , ceramics , rocks , and minerals .