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Depending on the environmental conditions present at the time of their formation, concretions can be created by either concentric or pervasive growth. [11] [12] In concentric growth, the concretion grows as successive layers of mineral precipitate around a central core. This process results in roughly spherical concretions that grow with time.
Similar to the marine nodules, concretion layers are defined based on iron and manganese content as well as their combination. [2] High iron content nodules appear a red or brown color, while high manganese content appears black or grey. [2] The dominant metal oxide is related to the elements enriched in the nodule.
Iron(III) oxide is a product of the oxidation of iron. It can be prepared in the laboratory by electrolyzing a solution of sodium bicarbonate, an inert electrolyte, with an iron anode: 4 Fe + 3 O 2 + 2 H 2 O → 4 FeO(OH) The resulting hydrated iron(III) oxide, written here as FeO(OH), dehydrates around 200 °C. [18] [19] 2 FeO(OH) → Fe 2 O 3 ...
Iron is stored in many organisms in the form of ferritin, which is a ferrous oxide encased in a solubilizing protein sheath. [ 10 ] Species of bacteria , including Shewanella oneidensis , Geobacter sulfurreducens and Geobacter metallireducens , use iron oxides as terminal electron acceptors .
The iron forming these concretions came from the breakdown of iron-bearing silicate minerals by weathering to form iron oxide coatings on other grains. During later diagenesis of the Navajo Sandstone while deeply buried, reducing fluids , likely hydrocarbons , dissolved these coatings.
Chemical weathering of rocks that leads to the formation of Liesegang rings typically involves the diffusion of oxygen in subterranean water into pore space containing soluble ferrous iron. [7] Liesegang rings usually cut across layers of stratification and occur in many types of rock, some of which more commonly include sandstone and chert . [ 3 ]
The formation of frost dendrites on a window is another common example of this crystal growth. Concretions are sometimes thought to be fossils, and occasionally one contains a fossil, but are generally not fossils themselves. Chert or flint nodules in limestone can often take forms that resemble fossils.
Iron(II,III) oxide, or black iron oxide, is the chemical compound with formula Fe 3 O 4. It occurs in nature as the mineral magnetite . It is one of a number of iron oxides , the others being iron(II) oxide (FeO), which is rare, and iron(III) oxide (Fe 2 O 3 ) which also occurs naturally as the mineral hematite .