Search results
Results From The WOW.Com Content Network
Optical activity is reciprocal, i.e. it is the same for opposite directions of wave propagation through an optically active medium, for example, clockwise polarization rotation from the point of view of an observer.
In all materials the rotation varies with wavelength. The variation is caused by two quite different phenomena. The first accounts in most cases for the majority of the variation in rotation and should not strictly be termed rotatory dispersion. It depends on the fact that optical activity is actually circular birefringence.
Recording optical rotation with a polarimeter: The plane of polarisation of plane polarised light (4) rotates (6) as it passes through an optically active sample (5). This angle is determined with a rotatable polarizing filter (7). In chemistry, specific rotation ([α]) is a property of a chiral chemical compound.
Determination of specific rotation: In order to determine a specific rotation of an optically active substance (say, sugar), the polarimeter tube is first filled with pure water and the analyzer is adjusted for equal darkness (both the halves should be equally dark) point. The position of the analyzer is noted with the help of the scale.
Michael Faraday holding a piece of glass of the type he used to demonstrate the effect of magnetism on polarization of light, c. 1857.. By 1845, it was known through the work of Augustin-Jean Fresnel, Étienne-Louis Malus, and others that different materials are able to modify the direction of polarization of light when appropriately oriented, [4] making polarized light a very powerful tool to ...
A half-wave plate rotates polarization by 90° A polarization rotator is an optical device that rotates the polarization axis of a linearly polarized light beam by an angle of choice. Such devices can be based on the Faraday effect, on birefringence, or on total internal reflection. [1]
The absorption of electromagnetic radiation by water depends on the state of the water. The absorption in the gas phase occurs in three regions of the spectrum. Rotational transitions are responsible for absorption in the microwave and far-infrared, vibrational transitions in the mid-infrared and near-infrared. Vibrational bands have rotational ...
Temperature can affect the rotation of light, which should be accounted for in the calculations. [] = / where: [α] λ T is the specific rotation. T is the temperature. λ is the wavelength of light. α is the angle of rotation.