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A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.
All chemical transformations pass through an unstable structure called the transition state, which is poised between the chemical structures of the substrates and products. The transition states for chemical reactions are proposed to have lifetimes near 10 −13 seconds, on the order of the time of a single bond vibration. No physical or ...
The Morse potential, named after physicist Philip M. Morse, is a convenient interatomic interaction model for the potential energy of a diatomic molecule.It is a better approximation for the vibrational structure of the molecule than the quantum harmonic oscillator because it explicitly includes the effects of bond breaking, such as the existence of unbound states.
Peak-to-peak amplitude (abbreviated p–p or PtP or PtoP) is the change between peak (highest amplitude value) and trough (lowest amplitude value, which can be negative). With appropriate circuitry, peak-to-peak amplitudes of electric oscillations can be measured by meters or by viewing the waveform on an oscilloscope .
An oscillator is a physical system characterized by periodic motion, such as a pendulum, tuning fork, or vibrating diatomic molecule.Mathematically speaking, the essential feature of an oscillator is that for some coordinate x of the system, a force whose magnitude depends on x will push x away from extreme values and back toward some central value x 0, causing x to oscillate between extremes.
Different fields of application have different definitions for the term. All the meanings are very similar in concept: In chemistry, the transmission coefficient refers to a chemical reaction overcoming a potential barrier; in optics and telecommunications it is the amplitude of a wave transmitted through a medium or conductor to that of the incident wave; in quantum mechanics it is used to ...
In acoustics, Stokes's law of sound attenuation is a formula for the attenuation of sound in a Newtonian fluid, such as water or air, due to the fluid's viscosity.It states that the amplitude of a plane wave decreases exponentially with distance traveled, at a rate α given by = where η is the dynamic viscosity coefficient of the fluid, ω is the sound's angular frequency, ρ is the fluid ...
As the excited state decays exponentially in time this effect produces a line with Lorentzian shape in terms of frequency (or wavenumber). Doppler broadening. This is caused by the fact that the velocity of atoms or molecules relative to the observer follows a Maxwell distribution, so the effect is dependent on temperature. If this were the ...