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  2. Rate equation - Wikipedia

    en.wikipedia.org/wiki/Rate_equation

    The order of reaction is a number which quantifies the degree to which the rate of a chemical reaction ... The slope of a graph of ... Chemical kinetics (3rd ed ...

  3. Phase transition - Wikipedia

    en.wikipedia.org/wiki/Phase_transition

    Under the Ehrenfest classification scheme, there could in principle be third, fourth, and higher-order phase transitions. For example, the Gross–Witten–Wadia phase transition in 2-d lattice quantum chromodynamics is a third-order phase transition, and the Tracy–Widom distribution can be interpreted as a third-order transition.

  4. Reaction rate constant - Wikipedia

    en.wikipedia.org/wiki/Reaction_rate_constant

    where A and B are reactants C is a product a, b, and c are stoichiometric coefficients,. the reaction rate is often found to have the form: = [] [] Here ⁠ ⁠ is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the ...

  5. Arrhenius equation - Wikipedia

    en.wikipedia.org/wiki/Arrhenius_equation

    In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...

  6. Van 't Hoff equation - Wikipedia

    en.wikipedia.org/wiki/Van_'t_Hoff_equation

    The Van 't Hoff equation relates the change in the equilibrium constant, K eq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, Δ r H ⊖, for the process. The subscript r {\displaystyle r} means "reaction" and the superscript ⊖ {\displaystyle \ominus } means "standard".

  7. Energy profile (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Energy_profile_(chemistry)

    In theoretical chemistry, an energy profile is a theoretical representation of a chemical reaction or process as a single energetic pathway as the reactants are transformed into products. This pathway runs along the reaction coordinate , which is a parametric curve that follows the pathway of the reaction and indicates its progress; thus ...

  8. Reactivity series - Wikipedia

    en.wikipedia.org/wiki/Reactivity_series

    The order of reactivity, as shown by the vigour of the reaction with water or the speed at which the metal surface tarnishes in air, appears to be Cs > K > Na > Li > alkaline earth metals, i.e., alkali metals > alkaline earth metals, the same as the reverse order of the (gas-phase) ionization energies.

  9. Periodic table - Wikipedia

    en.wikipedia.org/wiki/Periodic_table

    Periodic table of the chemical elements showing the most or more commonly named sets of elements (in periodic tables), and a traditional dividing line between metals and nonmetals. The f-block actually fits between groups 2 and 3 ; it is usually shown at the foot of the table to save horizontal space.