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A molecular sieve is a material with pores (voids or holes), having uniform size comparable to that of individual molecules, linking the interior of the solid to its exterior. These materials embody the molecular sieve effect , the preferential sieving of molecules larger than the pores.
Size-exclusion chromatography, also known as molecular sieve chromatography, [1] is a chromatographic method in which molecules in solution are separated by their shape, and in some cases size. [2] It is usually applied to large molecules or macromolecular complexes such as proteins and industrial polymers . [ 3 ]
The maximum size of the molecular or ionic species that can enter the pores of a zeolite is controlled by the dimensions of the channels. These are conventionally defined by the ring size of the aperture, where, for example, the term "eight-ring" refers to a closed-loop that is built from eight tetrahedrally coordinated silicon (or aluminium ...
In sieve analysis, the particle size distribution of a granular material is assessed by letting the material pass through a series of sieves of progressively smaller mesh size. In that case the equivalent spherical diameter corresponds to the equivalent sieve diameter, or the diameter of a sphere that just passes through a defined sieve pore.
In addition to their affinity for different gases, zeolites and some types of activated carbon may utilize their molecular sieve characteristics to exclude some gas molecules from their structure based on the size and shape of the molecules, thereby restricting the ability of the larger molecules to be adsorbed.
A sieve analysis (or gradation test) is a practice or procedure used in geology, civil engineering, [1] and chemical engineering [2] to assess the particle size distribution (also called gradation) of a granular material by allowing the material to pass through a series of sieves of progressively smaller mesh size and weighing the amount of material that is stopped by each sieve as a fraction ...
Gel permeation chromatography (GPC) [1] is a type of size-exclusion chromatography (SEC), that separates high molecular weight or colloidal analytes on the basis of size or diameter, typically in organic solvents. The technique is often used for the analysis of polymers.
MCM-41 consists of a regular arrangement of cylindrical mesopores that form a one-dimensional pore system. [3] It is characterized by an independently adjustable pore diameter, a sharp pore distribution, a large surface and a large pore volume.