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For a fully oriented molecule, the dipolar coupling for an 1 H-15 N amide group would be over 20 kHz, and a pair of protons separated by 5 Å would have up to ~1 kHz coupling. However the degree of alignment achieved by applying magnetic field is so low that the largest 1 H-15 N or 1 H-13 C dipolar couplings are <5 Hz. [19]
Magnetic dipole–dipole interaction, also called dipolar coupling, refers to the direct interaction between two magnetic dipoles. Roughly speaking, the magnetic field of a dipole goes as the inverse cube of the distance, and the force of its magnetic field on another dipole goes as the first derivative of the magnetic field. It follows that ...
The mechanisms of nuclear-spin energy-coupling have been extensively characterized and are described in the following articles: Angular momentum coupling, Magnetic dipole–dipole interaction, J-coupling, Residual dipolar coupling, Nuclear Overhauser effect, Spin–spin relaxation, and Spin saturation transfer. Alternatively, some nuclei in a ...
In nuclear chemistry and nuclear physics, J-couplings (also called spin-spin coupling or indirect dipole–dipole coupling) are mediated through chemical bonds connecting two spins. It is an indirect interaction between two nuclear spins that arises from hyperfine interactions between the nuclei and local electrons. [ 1 ]
The rotor iron retains a degree of residual magnetism when the generator is turned off. The generator is started with no load connected; the initial weak field induces a weak current in the rotor coils, which in turn creates an initial field current, increasing the field strength, thus increasing the induced current in the rotor, and so on in a ...
Magnetic dipole transitions describe the dominant effect of the coupling of the magnetic dipole moment of the electron to the magnetic part of the electromagnetic wave. They can be divided into two groups by the frequency at which they are observed: optical magnetic dipole transitions can occur at frequencies in the infrared, optical or ...
The two models for a dipole (current loop and magnetic poles), give the same predictions for the magnetic field far from the source. However, inside the source region they give different predictions.
The "feet" of the lineshape correspond to the situation when the principal axis of the coupling interaction is parallel to the magnetic field which is much less statistically relevant. Pake was the first to describe this lineshape and used it to extract the proton-proton distance from his experiments on a single crystal and powdered hydrates of ...