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Download as PDF; Printable version; ... Freezing point (°C) K f (°C⋅kg/mol) Data source; Aniline: ... List of boiling and freezing information of solvents.
The Frost diagram normally shows free-energy values above and below nE° = 0 and is scaled in integers. The y axis of the graph displays the free energy. Increasing stability (lower free energy) is lower on the graph, so the higher free energy and higher on the graph a species of an element is, the more unstable and reactive it is. [2]
The phenomenon of freezing-point depression has many practical uses. The radiator fluid in an automobile is a mixture of water and ethylene glycol. The freezing-point depression prevents radiators from freezing in winter. Road salting takes advantage of this effect to lower the freezing point of the ice it is placed on.
Freezing is a phase transition in which a liquid turns into a solid when its temperature is lowered below its freezing point. [ 1 ] [ 2 ] For most substances, the melting and freezing points are the same temperature; however, certain substances possess differing solid-liquid transition temperatures.
The term "cryoscopy" means "freezing measurement" in Greek. Freezing point depression is a colligative property, so ΔT depends only on the number of solute particles dissolved, not the nature of those particles. Cryoscopy is related to ebullioscopy, which determines the same value from the ebullioscopic constant (of boiling point elevation).
For pure elements or compounds, e.g. pure copper, pure water, etc. the liquidus and solidus are at the same temperature, and the term melting point may be used. There are also some mixtures which melt at a particular temperature, known as congruent melting. One example is eutectic mixture. In a eutectic system, there is particular mixing ratio ...
Freezing Point Depression and Related Phenomena". It was originally published in 1923 in volume 24 of a German-language journal Physikalische Zeitschrift . An English translation [ 21 ] : 217–63 of the article is included in a book of collected papers presented to Debye by "his pupils, friends, and the publishers on the occasion of his ...
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.