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This definition was refined by Ronald Gillespie in 1971, as any acid with an H 0 value lower than that of 100% sulfuric acid (−11.93). [3] George A. Olah prepared the so-called " magic acid ", so named for its ability to attack hydrocarbons , by mixing antimony pentafluoride (SbF 5 ) and fluorosulfonic acid (FSO 3 H). [ 4 ]
Sulfamic acid is preferable to hydrochloric acid in household use, due to its intrinsic safety. If inadvertently mixed with hypochlorite based products such as bleach , it does not form chlorine gas, whereas the most common acids would; the reaction ( neutralisation ) with ammonia , produces a salt, as depicted in the section above.
In chemistry, a nucleophile is a chemical species that forms bonds by donating an electron pair. All molecules and ions with a free pair of electrons or at least one pi bond can act as nucleophiles. Because nucleophiles donate electrons, they are Lewis bases. Nucleophilic describes the affinity of a nucleophile to bond with positively charged ...
where k and k 0 are the rate constants for a nucleophile and a standard (H 2 O). H is a measure of the basicity of the nucleophile relative to protons, as defined by the equation: = + where the pK a is that of the conjugate acid of the nucleophile and the constant 1.74 is the correction for the pK a of H 3 O +.
Protic solvents react with strong nucleophiles with good basic character in an acid/base fashion, thus decreasing or removing the nucleophilic nature of the nucleophile. The following table shows the effect of solvent polarity on the relative reaction rates of the S N 2 reaction of 1-bromobutane with azide (N 3 – ).
A typical mixture is 3 parts of concentrated sulfuric acid and 1 part of 30 wt. % hydrogen peroxide solution; [1] other protocols may use a 4:1 or even 7:1 mixture. A closely related mixture, sometimes called "base piranha", is a 5:1:1 mixture of water, ammonia solution (NH 4 OH, or NH 3 (aq)), and 30% hydrogen peroxide.
Alkali salts or base salts are salts that are the product of incomplete neutralization of a strong base and a weak acid. Rather than being neutral (as some other salts), alkali salts are bases as their name suggests. What makes these compounds basic is that the conjugate base from the weak acid hydrolyzes to form a basic solution.
Acid salts are a class of salts that produce an acidic solution after being dissolved in a solvent. Its formation as a substance has a greater electrical conductivity than that of the pure solvent. [1] An acidic solution formed by acid salt is made during partial neutralization of diprotic or polyprotic acids.