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For example, it can be used to convert methyl esters to carboxylic acids: [9] RCO 2 CH 3 + LiI → RCO 2 Li + CH 3 I. Similar reactions apply to epoxides and aziridines. Lithium iodide was used as a radiocontrast agent for CT scans. Its use was discontinued due to renal toxicity. Inorganic iodine solutions suffered from hyperosmolarity and high ...
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Lithium enolate formation can be generalized as an acid–base reaction, in which the relatively acidic proton α to the carbonyl group (pK =20-28 in DMSO) reacts with organolithium base. Generally, strong, non-nucleophilic bases, especially lithium amides such LDA, LiHMDS and LiTMP are used.
Substance Formula 0 °C 10 °C 20 °C 30 °C 40 °C 50 °C 60 °C 70 °C 80 °C 90 °C 100 °C Barium acetate: Ba(C 2 H 3 O 2) 2: 58.8: 62: 72: 75: 78.5: 77: 75
Strong acids, strong bases and soluble ionic salts that are not weak acids or weak bases are strong ... Triflic acid, CF 3 SO 3 H; Strong bases. Lithium hydroxide, LiOH;
The ECW model is a quantitative model that describes and predicts the strength of Lewis acid base interactions, −ΔH. The model assigned E and C parameters to many Lewis acids and bases. Each acid is characterized by an E A and a C A. Each base is likewise characterized by its own E B and C B. The E and C parameters refer, respectively, to ...
Typically lithium fluoride is mixed with beryllium fluoride to form a base solvent , into which fluorides of uranium and thorium are introduced. Lithium fluoride is exceptionally chemically stable and LiF/ BeF 2 mixtures ( FLiBe ) have low melting points (360 to 459 °C or 680 to 858 °F) and the best neutronic properties of fluoride salt ...
Hydroiodic acid (or hydriodic acid) is a colorless liquid. It is an aqueous solution of hydrogen iodide with the chemical formula H I. It is a strong acid, in which hydrogen iodide is ionized completely in an aqueous solution. Concentrated aqueous solutions of hydrogen iodide are usually 48% to 57% HI by mass. [2] An oxidized solution of ...