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Esters with the general formula R 1 SO 2 OR 2 are called sulfonic esters.Individual members of the category are named analogously to how ordinary carboxyl esters are named.For example, if the R 2 group is a methyl group and the R 1 group is a trifluoromethyl group, the resulting compound is methyl trifluoromethanesulfonate.
Methyl methanesulfonate (MMS), also known as methyl mesylate, is an alkylating agent and a carcinogen. It is also a suspected reproductive toxicant, and may also be a skin/sense organ toxicant. [ 1 ] It is used in cancer treatment.
If the nucleophile is an alcohol, the product is a sulfonate ester; if it is an amine, the product is a sulfonamide: [citation needed] RSO 2 Cl + R' 2 NH → RSO 2 NR' 2 + HCl. However, sulfonyl chlorides also react frequently as a source of RSO − 2 and Cl +. [6]
Methyl esters are esters of methanol. Subcategories. This category has only the following subcategory. M. Methylsulfates (4 P) Pages in category "Methyl esters" ...
In organosulfur chemistry, a sulfonyl group is either a functional group found primarily in sulfones, or a substituent obtained from a sulfonic acid by the removal of the hydroxyl group, similarly to acyl groups. [1]: 1470–1476
Salts and esters of methanesulfonic acid are known as mesylates (or methanesulfonates, as in ethyl methanesulfonate). It is hygroscopic in its concentrated form. Methanesulfonic acid can dissolve a wide range of metal salts, many of them in significantly higher concentrations than in hydrochloric acid (HCl) or sulfuric acid (H 2 SO 4). [3]
Methyl trifluoromethanesulfonate, also commonly called methyl triflate and abbreviated MeOTf, is the organic compound with the formula CF 3 SO 2 OCH 3. It is a colourless liquid which finds use in organic chemistry as a powerful methylating agent. [2] The compound is closely related to methyl fluorosulfonate (FSO 2 OCH 3).
In organosulfur chemistry, organosulfates are a class of organic compounds sharing a common functional group with the structure R−O−SO − 3. The SO 4 core is a sulfate group and the R group is any organic residue. All organosulfates are formally esters derived from alcohols and sulfuric acid (H 2 SO 4) although many