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Firstly, a pure chemical should appear in at least one chemical phase and can also be characterized by its phase diagram. Secondly, a pure chemical should prove to be homogeneous (i.e., a uniform substance that has the same composition throughout the material [2]). The perfect pure chemical will pass all attempts to separate and purify it further.
For pure elements or compounds, e.g. pure copper, pure water, etc. the liquidus and solidus are at the same temperature, and the term melting point may be used. There are also some mixtures which melt at a particular temperature, known as congruent melting. One example is eutectic mixture. In a eutectic system, there is particular mixing ratio ...
Electrolysis refers to the breakdown of substances using an electric current. This removes impurities in a substance that an electric current is run through; Sublimation is the process of changing of any substance (usually on heating) from a solid to a gas (or from gas to a solid) without passing through liquid phase. In terms of purification ...
If a substance can exist but is not thermodynamically stable (for example, a supercooled liquid), it is called a metastable state. A non - physical standard state is one whose properties are obtained by extrapolation from a physical state (for example, a solid superheated above the normal melting point, or an ideal gas at a condition where the ...
The melting point of a pure substance is always higher and has a smaller range than the melting point of an impure substance or, more generally, of mixtures. The higher the quantity of other components, the lower the melting point and the broader will be the melting point range, often referred to as the "pasty range".
The figure shows the schematic P-T diagram of a pure substance (as opposed to mixtures, which have additional state variables and richer phase diagrams, discussed below). The commonly known phases solid , liquid and vapor are separated by phase boundaries, i.e. pressure–temperature combinations where two phases can coexist.
A given pure compound has only one normal boiling point, if any, and a compound's normal boiling point and melting point can serve as characteristic physical properties for that compound, listed in reference books. The higher a compound's normal boiling point, the less volatile that compound is overall, and conversely, the lower a compound's ...
Yields may appear to be 100% or above when products are impure, as the measured weight of the product will include the weight of any impurities. [ 6 ] : 125 In their 2016 laboratory manual, Experimental Organic Chemistry , the authors described the "reaction yield" or "absolute yield" of a chemical reaction as the "amount of pure and dry ...