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Hydrogen isocyanide (HNC) is a linear triatomic molecule with C ∞v point group symmetry.It is a zwitterion and an isomer of hydrogen cyanide (HCN). [2] Both HNC and HCN have large, similar dipole moments, with μ HNC = 3.05 Debye and μ HCN = 2.98 Debye respectively. [3]
Hydrogen cyanide (formerly known as prussic acid) is a chemical compound with the formula HCN and structural formula H−C≡N. It is a highly toxic and flammable liquid that boils slightly above room temperature , at 25.6 °C (78.1 °F).
Isocyanic acid is a chemical compound with the structural formula HNCO, which is often written as H−N=C=O. It is a colourless, volatile and poisonous gas, condensing at 23.5 °C. It is the predominant tautomer and an isomer of cyanic acid (aka. cyanol) ( H−O−C≡N ), and the monomer of cyanuric acid .
Cyanogen is the chemical compound with the formula (C N) 2. The simplest stable carbon nitride, it is a colorless and highly toxic gas with a pungent odor. The molecule is a pseudohalogen. Cyanogen molecules consist of two CN groups ‒ analogous to diatomic halogen molecules, such as Cl 2, but far less oxidizing.
The C-N distance in isocyanides is 115.8 pm in methyl isocyanide.The C-N-C angles are near 180°. [3]Akin to carbon monoxide, isocyanides are described by two resonance structures, one with a triple bond between the nitrogen and the carbon and one with a double bond between.
Thiocyanic acid is a chemical compound with the formula H S C N and structure H−S−C≡N, which exists as a tautomer with isothiocyanic acid (H−N=C=S). [8] The isothiocyanic acid tautomer tends to dominate with the compound being about 95% isothiocyanic acid in the vapor phase. [9] Tautomerism between thiocyanic acid (left) and ...
Acetylenic substrates undergo the reaction; however the scope of this reaction is limited and yields are often low. [5] 1,4-Addition to imines has been observed in a few cases, although imines are often base labile. [5] Esters, [7] nitriles, [5] and other carbonyl derivatives also undergo conjugative hydrocyanation. When alkali metal cyanides ...
During this time cyanoacetylene, HC 3 N, formed through a series of ion-neutral reactions, with the final chemical reaction being: C 3 H 2 + N → HC 3 N + H. However, for time after 10,000 years the dominant reactions were neutral–neutral reactions and two reaction mechanisms for the formation of cyanopolyynes became possible. HCN + C 2 H 2 ...