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  2. Mayer's relation - Wikipedia

    en.wikipedia.org/wiki/Mayer's_Relation

    In the 19th century, German chemist and physicist Julius von Mayer derived a relation between the molar heat capacity at constant pressure and the molar heat capacity at constant volume for an ideal gas.

  3. Ideal gas law - Wikipedia

    en.wikipedia.org/wiki/Ideal_gas_law

    Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...

  4. Perfect gas - Wikipedia

    en.wikipedia.org/wiki/Perfect_gas

    In physics, engineering, and physical chemistry, a perfect gas is a theoretical gas model that differs from real gases in specific ways that makes certain calculations easier to handle. In all perfect gas models, intermolecular forces are neglected. This means that one can neglect many complications that may arise from the Van der Waals forces.

  5. Collision frequency - Wikipedia

    en.wikipedia.org/wiki/Collision_frequency

    Collision frequency describes the rate of collisions between two atomic or molecular species in a given volume, per unit time. In an ideal gas, assuming that the species behave like hard spheres, the collision frequency between entities of species A and species B is: [1]

  6. Van der Waals constants (data page) - Wikipedia

    en.wikipedia.org/wiki/Van_der_Waals_constants...

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  7. Relations between heat capacities - Wikipedia

    en.wikipedia.org/wiki/Relations_between_heat...

    This is a derivation to obtain an expression for for an ideal gas. An ideal gas has the equation of state: = where P = pressure V = volume n = number of moles R = universal gas constant T = temperature. The ideal gas equation of state can be arranged to give:

  8. Van der Waals equation - Wikipedia

    en.wikipedia.org/wiki/Van_der_Waals_equation

    Figures A and C show the surface calculated from the van der Waals equation. Note that whereas the ideal gas surface is relatively uniform, the van der Waals surface has a distinctive "fold". This fold develops from a critical point defined by specific values of pressure, temperature, and molar volume.

  9. Free molecular flow - Wikipedia

    en.wikipedia.org/wiki/Free_molecular_flow

    Gas flow can be grouped in four regimes: For Kn≤0.001, flow is continuous, and the Navier–Stokes equations are applicable, from 0.001<Kn<0.1, slip flow occurs, from 0.1≤Kn<10, transitional flow occurs and for Kn≥10, free molecular flow occurs. [6] In free molecular flow, the pressure of the remaining gas can be considered as effectively ...