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In 1890, Rydberg proposed on a formula describing the relation between the wavelengths in spectral lines of alkali metals. [2]: v1:376 He noticed that lines came in series and he found that he could simplify his calculations using the wavenumber (the number of waves occupying the unit length, equal to 1/λ, the inverse of the wavelength) as his unit of measurement.
For the hydrogen atom Bohr starts with his derived formula for the energy released as a free electron moves into a stable circular orbit indexed by : [28] = The energy difference between two such levels is then: = = Therefore, Bohr's theory gives the Rydberg formula and moreover the numerical value the Rydberg constant for hydrogen in terms of ...
The hydrogen spectral series can be expressed simply in terms of the Rydberg constant for hydrogen and the Rydberg formula. In atomic physics, Rydberg unit of energy, symbol Ry, corresponds to the energy of the photon whose wavenumber is the Rydberg constant, i.e. the ionization energy of the hydrogen atom in a simplified Bohr model.
The concepts of the Rydberg formula can be applied to any system with a single particle orbiting a nucleus, for example a He + ion or a muonium exotic atom. The equation must be modified based on the system's Bohr radius ; emissions will be of a similar character but at a different range of energies.
The model's key success lay in explaining the Rydberg formula for the spectral emission lines of atomic hydrogen by using the transitions of electrons between orbits. [24]: 276 While the Rydberg formula had been known experimentally, it did not gain a theoretical underpinning until the Bohr model was introduced. Not only did the Bohr model ...
The Rydberg states [1] of an atom or molecule are electronically excited states with energies that follow the Rydberg formula as they converge on an ionic state with an ionization energy. Although the Rydberg formula was developed to describe atomic energy levels, it has been used to describe many other systems that have electronic structure ...
The version of the Rydberg formula that generated the Lyman series was: [2] = (= +) where n is a natural number greater than or equal to 2 (i.e., n = 2, 3, 4, .... Therefore, the lines seen in the image above are the wavelengths corresponding to n = 2 on the right, to n → ∞ on the left.
According to the quantum theory of the hydrogen atom proposed by Niels Bohr in 1913, an atom can have only certain energy levels. Absorption or emission of a particle of light or photon corresponds to a transition between two possible energy levels, and the photon energy equals the difference between their two energies.